“…Application of the high synthesis temperature in the case of water treatment leads to formation not only of needle shape, but also round shape crystals with an average size 128 ± 42 nm ( Table A3 ) typically observed in the case of hydrothermal synthesis of steel slag [9] , [10] . A survey of literature shows that the assignment of this type of crystals is controversial, as they can be attributed to different phases – TiO 2 (anatase [31] , [32] or rutile [32] ), Fe 2 O 3 [33] , [34] or CaCO 3 [30] , [35] . Moreover, presence of the numerous impurities complicates the process of phase identifications even further, as illustrated for Fe 2 O 3 doped with inorganic cations [33] .…”