The Influence of the Magnesium-to-Phosphate Molar Ratio on Magnesium Potassium Phosphate Cement Properties Using Either Wollastonite or Volcanic Ash as Fillers

Abstract

The use of the fillers wollastonite and volcanic ash for the formulation of magnesium phosphate cements prepared at magnesium-to-phosphate molar ratios of 2, 3 and 4 has been investigated, with the objective of evaluating these formulations for the encapsulation of aluminium radioactive waste. The workability, mechanical strength, dimensional stability, pH, chemical composition and mineralogical properties of cement pastes and mortars were examined. All cement pastes presented fast setting, and the workability was only good at 3 and 4 M. The cement mortars presented high compressive strength and dimensional stability. K-struvite was confirmed as the sole reaction product of the reaction for all formulations. The pH of the cement pastes, measured in suspensions, achieved values in the range of 7.8 to 9.5 after the first days of setting, exceeding pH 8.5 for the 2 and 3 M formulations. pH values below 8.5 are theoretically preferred to avoid potential aluminium corrosion. Both fillers presented adequate characteristics (good workability, chemical compatibility) to be used in the formulation of magnesium phosphate cements. The increasing magnesium-to-phosphate molar ratio prevented unwanted efflorescence and increased the mechanical stability of the cement.