Abstract. By using optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), electron back scattered diffraction (EBSD) and tensile test, the effect of annealing temperature on microstructure and mechanical properties of a high Al-low Si TRIP steel was investigated. The results show that TRIP effect can be obtained when annealing temperature is above A c3 due to the existence of -ferrite in this high Al-low Si TRIP steel. That is to say, the microstructure consisting of ferrite, bainite and retained austenite can be obtained when annealing temperature is above A c3 . Furthermore, the tensile strength and the product of strength and elongation decrease with increasing annealing temperature when annealing temperature is above A c3 .