2004
DOI: 10.1016/j.msec.2004.08.045
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The influence of starch gelatinization on the rheological, thermal, and morphological properties of poly(ɛ-caprolactone) with corn starch blends

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Cited by 36 publications
(21 citation statements)
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“…The absence of significant variations of the PCL crystallinity as the starch concentration grows has also been reported in previous works on this same blend system (Avella et al, 2000). However, the reduction in the concentration of 3 D ordered PCL domains has also been reported after starch addition (Cai et al, 2014;Rosa, Guedes, Pedroso, & Calil, 2004;Rosa, Lopes, & Calil, 2005;Wu, 2003). On the other hand, Wang et al (2005) found for the 70/30 blend composition a very small increase from 2 to 3% in the PCL crystallinity after Differential Scanning Calorimetry runs when different cooling rates are chosen; the crystallization rate being higher for their blend than for pure PCL, starch is viewed as an effective nucleation agent for PCL.…”
Section: Resultssupporting
confidence: 85%
“…The absence of significant variations of the PCL crystallinity as the starch concentration grows has also been reported in previous works on this same blend system (Avella et al, 2000). However, the reduction in the concentration of 3 D ordered PCL domains has also been reported after starch addition (Cai et al, 2014;Rosa, Guedes, Pedroso, & Calil, 2004;Rosa, Lopes, & Calil, 2005;Wu, 2003). On the other hand, Wang et al (2005) found for the 70/30 blend composition a very small increase from 2 to 3% in the PCL crystallinity after Differential Scanning Calorimetry runs when different cooling rates are chosen; the crystallization rate being higher for their blend than for pure PCL, starch is viewed as an effective nucleation agent for PCL.…”
Section: Resultssupporting
confidence: 85%
“…It was shown previously that gelatinized starch increases water absorption. [26] When barley was combined with WPC80 or CP, the solubility of the raw products increased, but decreased significantly (p < 0.05) after extrusion. This decrease in solubility can be attributed to denaturation of the proteins which has been shown to cause loss of solubility.…”
Section: Barleymentioning
confidence: 93%
“…Polycaprolactone (PCL) offers interesting potential for low temperature thermoforming [5] and proven biocompatibility, biodegradability, and flexibility [6].…”
Section: Introductionmentioning
confidence: 99%