The influence of micellization ofn-decylamine on its basicity and reactivity toward carboxylic acid esters

Mirgorodskaya, A. B.; Kudryavtseva, L. A.; Ivanov, B. E.

doi:10.1007/bf01433970

Cited by 4 publications

(2 citation statements)

References 3 publications

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“…Earlier we have studied the kinetic properties of primary aliphatic amines in various self-organized solutions and have discussed the peculiarities of microemulsion influence on the rate and mechanism of nucleophilic substitution processes [10,11]. However, the presence of reactants in the system can produce structural changes in the microemulsion medium and the aim of this study is to reveal the influence of primary long-chain amines on the structural properties of microemulsion.…”

Section: Introductionmentioning

confidence: 99%

Effects of solubilized dodecylamine on the microstructure of cetylpyridinium bromide-n-butanol-hexane-water system studied by pulsed-gradient spin echo NMR and ESR spin label methods

et al. 2003

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The effect of solubilized dodecylamine (DDA) on the structure of the cetylpyridinium bromide-n-butanol-hexane-water microemulsions has been studied by the Fourier-transform pulsed-gradient spin-echo ~H nuclear magnetic resonance and the electron spin resonance spin label method. The sample compositions were chosen to examine three different microemulsion structures: oil-in-water, water-in-oil and bicontinuous. In all systems the DDA mo|ecules are shown to be incorporated into the oil-water interface, resulting in essential changes in the microemulsion structure. In the micellar systems the DDA emergence in the interface causes an increase of the micelle size and a redistribution of butanol and water between micelle and bulk phases. In the oil-in-water mir of amine-containing systems the quantity of micellized butanol and water decreases. In the water-in-oil microemulsions the introduction of DDA leads to an increase of butartol and water involved in the micelle formation. The redistribution of butanol and water between polar and organic phases in the microemulsions would be expected to cause changes in the bicontinuous structure.

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Section: Introductionmentioning

confidence: 99%

Effects of solubilized dodecylamine on the microstructure of cetylpyridinium bromide-n-butanol-hexane-water system studied by pulsed-gradient spin echo NMR and ESR spin label methods

et al. 2003

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“…[1][2][3] In the presence of surfactants, long-chain amines form mixed micelles which have some quite new properties. 4,5 The influence of the mixed micelles formation in the presence of amines on their reactivity has not been practically studied up to now.…”

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confidence: 99%

Catalysis of the hydrolysis of phosphorus acids esters by the mixed micelles of long-chain amines and cetylpyridinium bromide

Mirgorodskaya

Kudryavtseva

Zuev

et al. 1999

Mendeleev Communications

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N-Alkylamines-Based Micelles Aggregation Number Determination by Fluorescence Techniques

et al. 2011

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The influence of micellization ofn-decylamine on its basicity and reactivity toward carboxylic acid esters

Cited by 4 publications

References 3 publications

Effects of solubilized dodecylamine on the microstructure of cetylpyridinium bromide-n-butanol-hexane-water system studied by pulsed-gradient spin echo NMR and ESR spin label methods

Effects of solubilized dodecylamine on the microstructure of cetylpyridinium bromide-n-butanol-hexane-water system studied by pulsed-gradient spin echo NMR and ESR spin label methods

Catalysis of the hydrolysis of phosphorus acids esters by the mixed micelles of long-chain amines and cetylpyridinium bromide

N-Alkylamines-Based Micelles Aggregation Number Determination by Fluorescence Techniques

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