The onset of Soret-driven convection in a nanoparticles suspension heated from above is analyzed theoretically based on linear theory and relative instability concept. A new set of stability equations are derived and solved by using the dominant mode method. The dimensionless critical time τ c to mark the onset of instability is presented here as a function of the Rayleigh number, the Lewis number and the separation ratio. Available experimental data indicate that for large Rayleigh number convective motion is detected starting from a certain time τ≈3τ c . This means that the growth period of initiated instabilities is needed for convective motion to be detected experimentally. It seems evident that during τ c ≤τ≤3τ c convective motion is relatively very weak and the primary diffusive transfer is dominant.
INTRODUCITONThermal convection in binary mixtures shows quite different characteristics from those in pure fluids [1][2][3][4]. If the suspension of nanoparticles is under consideration, the spatiotemporal properties of convection are much more complex than those of pure fluids or molecular solutions due to the influence of thermal diffusion, i.e., Soretinduced concentration gradients and also the extremely small particle mobility which can be reflected by the Lewis number Le≤10 −4 [5-8]. Here Le(=D C /α) is the Lewis number, D C the diffusion coefficient, α the thermal diffusivity, respectively. The relative importance of the Soret effect with respect to weak solutal diffusion is measured by the separation ratio ψ(=(β C /β T )(D T /D C )), where D T is the Soret diffusion coefficient, and β T (=−ρ −1 (∂ρ/∂T)) and β C (=ρ −1 (∂ρ/∂C)) are the thermal and the solutal expansion coefficient, respectively. For the case of ψ =0 double diffusive convection sets in when Ra+Ra s ≥1708 [9], where Ra(=gβ T ∆Td 3 /αν) is the thermal Rayleigh number and Ra s =(gβ C ∆Cd 3 /Dν) the solutal Rayleigh number, respectively.For non-vanishing ψ, however, the external temperature gradient induces concentration variations and these create the buoyancy force.