The Influence of Hydroxylated Carbon Nanotubes on Epoxy Resin Composites

Zhang, Jiaoxia; Zheng, Yaping; Zhou, Haijun; Zhang, Jing; Zou, Jun

doi:10.1155/2012/518392

Cited by 7 publications

(7 citation statements)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…26 Zhang et al investigated the influence of the hydroxy functionalized MWCNTs on gel time of the MWCNT/epoxy resin nanocomposites. 27 They found that the gel time decreases with the increase of the MWCNTs content and is the shortest for 5% of MWCNT loading. This indicated that hydroxylated MWCNTs accelerated the curing reaction and enhanced the reactivity of resin at low temperature.…”

Section: Results and Discussion Pet Glycolysismentioning

confidence: 98%

“…This indicated that hydroxylated MWCNTs accelerated the curing reaction and enhanced the reactivity of resin at low temperature. 27 Due to differences in curing mechanisms caused by the presence of modified MWCNT, it was of interest to study of the effect of vinyl-modified MWCNT on the curing behavior of UPe/m-MWCNT nanocomposites. Among the Figure 4.…”

Section: Results and Discussion Pet Glycolysismentioning

confidence: 99%

See 1 more Smart Citation

Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites

Tasić

Rušmirović

Nikolić

et al. 2016

Journal of Composite Materials

View full text Add to dashboard Cite

Production of high-performance nanocomposite materials obtained from unsaturated polyester resin, based on products of the waste poly(ethylene terephthalate) recycling, and modified multi-walled carbon nanotubes is presented. Di-hydroxy functional glycolysates, synthesized by catalytic depolymerization of poly(ethylene terephthalate) with propylene glycol, were used for the unsaturated polyester resin synthesis. The structure of the obtained glycolysis product and unsaturated polyester resin were characterized by using FTIR and NMR spectroscopy, and by acid, iodine, and hydroxyl value. Nanofillers were prepared by direct and two-step amidation of oxidized multi-walled carbon nanotubes. Direct amidation with diallylamine produced multi-walled carbon nanotube-diallylamine reactive nanofiller. Two-step modification with diamines: hexamethylenediamine and p-phenylenediamine gave multi-walled carbon nanotubehexamethylenediamine and multi-walled carbon nanotube-p-phenylenediamine nanofiller, respectively, whose amidation with methyl ester of linseed oil fatty acids gave multi-walled carbon nanotube-hexamethylenediamine/methyl ester of linseed oil fatty acid and multi-walled carbon nanotube-p-phenylenediamine/methyl ester of linseed oil fatty acid nanofiller, respectively. Influences of vinyl functionalities on mechanical properties of nanocomposite were analyzed from tensile strength ( b ), elongation (" b ) and Young's modulus (E) determination. An increase of 97.4, 119 and 139% of b was obtained for nanocomposites with addition of 0.25 wt.% of diallylamine, p-phenylenediamine/methyl ester of linseed oil fatty acid and hexamethylenediamine/methyl ester of linseed oil fatty acid multi-walled carbon nanotubes, respectively. Short techno-economic analysis, performed on the basis of fixed and variable unsaturated polyester resin production costs, showed satisfactory potential profit, which could be realized by the implementation of the presented technology.

show abstract

Section: Results and Discussion Pet Glycolysismentioning

confidence: 98%

Section: Results and Discussion Pet Glycolysismentioning

confidence: 99%

Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites

Tasić

Rušmirović

Nikolić

et al. 2016

Journal of Composite Materials

View full text Add to dashboard Cite

show abstract

“…Epoxy resin/Graphene nanocomposites were prepared to improve different properties such as electrical, mechanical, rheological, thermal properties among others [18][19][20][21][22][23][24][25][26]. Moreover, studies related to functionalization of graphene for better dispersion and comparison with other nano-carbon materials such as carbon nanotubes were also demonstrated [27][28][29]. The results depicted that the targeted improved properties are better in case of incorporation of graphene in the epoxy matrix than in case of carbon nanotubes.…”

Section: Introductionmentioning

confidence: 99%

Epoxy resin reinforced with graphene derivatives: physical and dielectric properties

Rehim

Turky

2022

J Polym Res

View full text Add to dashboard Cite

Epoxy resins are important industrial polymers due to their versatile properties and ease of preparation. They are used on a large scale in coating and adhesives applications. Epoxy resins are prepared by photo-curing technique or thermal curing method in presence of different hardeners. The first method is used for small areas while the latter is utilized mainly for coating applications. Graphene and its oxide have proved themselves as good fillers for epoxy resin since the formed composites demonstrated enhanced mechanical, thermal and electrical properties. This article gives insight view for synthesis techniques and properties of these composites with a deep discussion for electrical and dielectric investigations of epoxy resins loaded with threshold concentration of graphene oxide. A case study of dielectric properties of epoxy resin/modified graphene oxide composite, is presented in which effect of curing technique on dielectric behavior is explored. Although the amount of filler was kept at the threshold concentration (1% by weight) obvious change in the dielectric properties could be observed unlike the rest of properties.

show abstract

“…Thermoset-based composites are materials that have had an innovative development in recent years. According to the reported studies, among the optimal fillers used for polymeric (nano)composites with superior mechanical, electrical, and chemical properties are the carbon nanotubes and grapheme [ 14 , 15 , 16 , 17 , 18 ]. Unfortunately, this type of material leads to a high production cost.…”

Section: Introductionmentioning

confidence: 99%

Hydrothermal Carbon as Reactive Fillers to Produce Sustainable Biocomposites with Aromatic Bio-Based Epoxy Resins

et al. 2021

View full text Add to dashboard Cite

Thiswork is focused on the development of sustainable biocomposites based on epoxy bioresin reinforced with a natural porous material (hydrochar, HC) that is the product of spruce bark wastes subjected to hydrothermal decomposition. To identify the influence of hydrochar as a reinforcing material on the designed composites, seven formulations were prepared and tested. An aromatic epoxy monomer derived from wood biomass was used to generate the polymeric matrix, and the formulations were prepared varying the filler concentration from 0 to 30 wt %. The reactivity of these formulations, together with the structural, thermal, and mechanical properties of bio-based resin and biocomposites, are investigated. Surprisingly, the reactivity study performed by differential scanning calorimetry (DSC) revealed that HC has a strong impact on polymerization, leading to an important increase in reaction enthalpy and to a decrease of temperature range. The Fourier Transform Infrared Spectroscopy (FT-IR) investigations confirmed the chemical bonding between the resin and the HC, while the dynamic mechanical analysis (DMA) showed increased values of crosslink density and of storage moduli in the biocomposites products compared to the neat bioresin. Thermogravimetric analysis (TGA) points out that the addition of hydrochar led to an improvement of the thermal stability of the biocomposites compared with the neat resorcinol diglycidyl ether (RDGE)-based resin (T5% = 337 °C) by ≈2–7 °C. Significantly, the biocomposites with 15–20 wt % hydrochar showed a higher stiffness value compared to neat epoxy resin, 92SD vs. 82SD, respectively.

show abstract

The Influence of Hydroxylated Carbon Nanotubes on Epoxy Resin Composites

Cited by 7 publications

References 10 publications

Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites

Effect of the vinyl modification of multi-walled carbon nanotubes on the performances of waste poly(ethylene terephthalate)-based nanocomposites

Epoxy resin reinforced with graphene derivatives: physical and dielectric properties

Hydrothermal Carbon as Reactive Fillers to Produce Sustainable Biocomposites with Aromatic Bio-Based Epoxy Resins

Contact Info

Product

Resources

About