“…With more Si entering the Fe substrate, γ-Fe(Si) phase starts to transform to α-Fe(Si) phase. Knowing that Si atoms diffuse more quickly in α-Fe(Si) phase than in γ-Fe(Si) [20,21], Si penetration can be suggested to be controlled by its migration through the α-Fe(Si) and γ-Fe(Si) interface. The argument is confirmed by the result that a critical point at which the Si concentration dropped quickly appears around 1.9 wt.%, as shown in Fig.…”