2023
DOI: 10.3390/molecules28207214
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The Influence of an Extended π Electron System on the Electrochemical Properties and Oxidizing Activity of a Series of Iron(III) Porphyrazines with Bulky Pyrrolyl Substituents

Tomasz Koczorowski,
Tomasz Rębiś

Abstract: The present study investigates four iron(II/III) porphyrazines with extending pyrrolyl peripheral substituents to understand the impact of introduced phenyl rings on the macrocycle’s electrochemical and spectroelectrochemical properties as well as their activity in oxidation reactions. The electrochemical studies showed six well-defined redox processes and quasi-reversible one-electron transfers—two originating from the iron cation and four related to the ring. Adding phenyl rings to the periphery increased th… Show more

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