The Influence of Ag+ ions on the kinetics of oxidation of Fe(phen)2+3 by peroxodisulphate in neutral aqueous solution

Oxidation of tris(1, 10-phenanthroline)iron(II) ion by iodate and periodate ions in neutral medium

“…The Fe(phen)2 (OH),' ion, created in reaction (9), undergoes the dimerization to the final product according to: [(phen), Fe(OH)2 Fe(phen),14 ' (24) Thus, in the excess of iodate the expression (20) reduces to:…”

Kinetics and Mechanism of Ag (I) Catalysis in Peroxodisulphate Oxidation of Tris(2,2´-Bipyridine)Fe(II) in Aqueous Acid Media

“…Kinetics of the influence of Ag + ions on the oxidation of [Fe(1, 3 ] 2+ by peroxodisulphate in neutral medium has been investigated by Cyfert (1983). Experiments on Ag + catalysed oxidation of [Co(II) EDTA] by S 2O8 2have also been reported (Begum and Rasheed, 2001).…”