The inference of interfacial properties from capillary wave experiments. I. systems with negligible surface viscosity

Mayer, E.; Eliassen, J. D.

doi:10.1016/0021-9797(71)90285-2

Cited by 22 publications

(3 citation statements)

References 11 publications

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“…The pioneers of surface research like Traube, von Szyszkowski, Langmuir, , Rehbinder, Frumkin, Harkins, and others used these amphiphiles. These investigations cover the adsorbed layers' thermodynamic, − kinetic, − electric, ,,− ,,− optical, − and surface- rheological − …”

Section: Introductionmentioning

confidence: 99%

“…The pioneers of surface research like Traube, 1 von Szyszkowski, 2 Langmuir, 3,6 Rehbinder, 4 Frumkin, 5 Harkins, 7 and others used these amphiphiles. These inves-tigations cover the adsorbed layers' thermodynamic, kinetic, 22-33 electric, 5,8,[12][13][14]20,[34][35][36][37][38][39][40][41] optical, [42][43][44][45][46][47][48][49][50] rheological [51][52][53][54][55][56][57][58][59][60][61][62][63][64][65][66][67][68] properties. (For the thermodynamic properties of insoluble monolayers we have included here only papers that were evaluated for the purpose of this work.)…”

Section: Introductionmentioning

confidence: 99%

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Adsorption Properties of Soluble, Surface-Chemically Puren-Alkanoic Acids at the Air/Water Interface and the Relationship to Insoluble Monolayer and Crystal Structure Properties

et al. 2003

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The adsorption properties of soluble, surface-chemically pure n-alkanoic acids at the air/water interface were investigated by evaluating equilibrium surface tension and surface potential versus concentration isotherms. There is no transition-like change in the adsorption isotherms of the n-alkanoic acids between n-pentanoic (C5) and n-undecanoic acid (C11). The isotherms are evaluated by the two-state approach to the adsorption equation and by the Gibbs equation. The nondissociated n-alkanoic acids' surface area demand per molecule adsorbed is not constant within the homologous series but decreases with increasing chain length until it approaches the (almost constant) value of the insoluble homologues. The limiting surface area demand per molecule adsorbed of the soluble n-alkanoic acids is compared with the corresponding data of the insoluble homologues obtained from surface pressure versus surface area isotherms as well as from crystal structure analyses. Standard free enthalpies of adsorption, limiting cross-sectional areas, and surface interaction parameters reveal a distinct effect of alternation within the homologous series. Interestingly, also the Henry constants are subject to the even/odd phenomenon. This is explained by the even and odd homologues' different surface arrangement of their terminal methyl groups with respect to the interface. The linear relationships describing the chain length dependences of the standard free enthalpy of adsorption and of the surface interaction parameter hold for chain lengths in the range 6 ≤ n C ≤ 11. n-Pentanoic acid has a somewhat different characteristic. Unlike the shorter chain homologues' adsorption, the adsorption of n-dodecanoic acid cannot be described by a monotonically proceeding process but seems to include also processes of association.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Adsorption Properties of Soluble, Surface-Chemically Puren-Alkanoic Acids at the Air/Water Interface and the Relationship to Insoluble Monolayer and Crystal Structure Properties

et al. 2003

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“…Equation 13 is the Laplace equation that includes the conventional mean curvature term, but in addition one should allow for the possibility that what may appear to be higher order curvature effects can be important. 55,6 The two that have been classified by Elias-sen55,8 are that of torsion and bending; in which case several additional terms would be included in the Laplace equation.…”

Section: Experimental Monolayer Dynamicsmentioning

confidence: 99%

Dynamics, structure, and function of interfacial regions

Mann¹

1985

Langmuir

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NO for the two opposite orientations can be estimated. This anisotropy is consistent with what is found to explain the NO anisotropy in the desorption rate from Pt(lll). In addition, the anisotropy scales appropriately with the anisotropy of NO on Ag(lll), a considerably weaker molecule-surface interaction. The degree of anisotropy in this case is obtained from fitting scattered rotational quantum state distributions.28,29 The quality of the experiments allow an accurate modeling of the anisotropy and consequent dynamics. The falloff in sticking probability with J state, and by detailed balancing the high c/-state deficiencies in thermal desorption, is shown to be a general result of orientational anisotropy.25Molecular anisotropy is thus seen to play an important role in adsorption, via the rotational state dependence of (28) Muhlhausen, C. W.; Tully, J. C., private communicationunpublished results.(29) Kleyn, A.

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Dynamic Surface Tension and Capillary Waves

Mann

1984

Surface and Colloid Science

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The inference of interfacial properties from capillary wave experiments. I. systems with negligible surface viscosity

Cited by 22 publications

References 11 publications

Adsorption Properties of Soluble, Surface-Chemically Puren-Alkanoic Acids at the Air/Water Interface and the Relationship to Insoluble Monolayer and Crystal Structure Properties

Adsorption Properties of Soluble, Surface-Chemically Puren-Alkanoic Acids at the Air/Water Interface and the Relationship to Insoluble Monolayer and Crystal Structure Properties

Dynamics, structure, and function of interfacial regions

Dynamic Surface Tension and Capillary Waves

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