The exacerbation of air pollution during spring in Yunnan province, China, has attracted widespread attention. However, many studies have focused solely on the impacts of anthropogenic emissions while ignoring the role of natural processes. This study used satellite data spanning 21 years from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Atmospheric Infrared Sounder (AIRS) to reveal two natural processes closely related to springtime ozone (O3) and PM2.5 pollution: stratospheric intrusions (SIs) and cross-border transport of biomass burning (BB). We aimed to assess the mechanisms through which SIs and cross-border BB transport influence O3 and PM2.5 pollution in Southwestern China during the spring. The unique geographical conditions and prevalent southwest winds are considered the key driving factors for SIs and cross-border BB transport. Frequent tropopause folding provides favorable dynamic conditions for SIs in the upper troposphere. In the lower troposphere, the distribution patterns of O3 and stratospheric O3 tracer (O3S) are similar to the terrain, indicating that O3 is more likely to reach the surface with increasing altitude. Using stratospheric tracer tagging methods, we quantified the contributions of SIs to surface O3, ranging from 6 to 31 ppbv and accounting for 10–38% of surface O3 levels. Additionally, as Yunnan is located downwind of Myanmar and has complex terrain, it provides favorable conditions for PM2.5 and O3 generation from cross-border BB transport. The decreasing terrain distribution from north to south in Yunnan facilitates PM2.5 transport to lower-elevation border cities, whereas higher-elevation cities hinder PM2.5 transport, leading to spatial heterogeneity in PM2.5. This study provides scientific support for elucidating the two key processes governing springtime PM2.5 and O3 pollution in Yunnan, SIs and cross-border BB transport, and can assist policymakers in formulating optimal emission reduction strategies.
