The hydration of cations in heavy water

Vdovenko, V.M.; Gurikov, Yu. V.; Legin, E. K.

doi:10.1007/bf01116807

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2020

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“…In general, the stronger H-bonding in D 2 O leads to significant differences in its solvation behaviour when compared to H 2 O. 23,24 In the case of ion pairs or clusters, D 2 O would be expected to favour aggregation, and has previously been suggested to decrease the dissociation constant of the ion pair Pb(NO 3 ) + , 25 as well as favouring the exchange of water for Cl À (i.e. formation of an ion pair) in several transition metal complexes.…”

Section: Introductionmentioning

confidence: 99%