The host behaviour of two compounds, bearing tricyclic fused ring systems, in mixtures of cyclohexanone and its three isomeric methylcyclohexanones
Brandon Barnardo,
Benita Barton,
Eric C Hosten
Abstract:Compounds N,N’-bis(9-phenyl-9-xanthenyl)propane-1,3-diamine (H1) and N,N’-bis(9-phenyl-9-xanthenyl)butane-1,4-diamine (H2) were assessed for their host behaviour in cyclohexanone (CYC) and 2-, 3- and 4-methylcyclohexanone (2MeCYC, 3MeCYC and 4MeCYC) through crystallization experiments from these potential guest solvents. It was thus shown that H1 possessed the ability to enclathrate CYC (only), while all four cyclohexanones formed complexes with H2. Thermal analyses and SCXRD revealed that those guest species … Show more
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