The homogeneous demethylation of toluene?A study of the basic parameters of the process at 750?790U

Gonikberg, M. G.; Dorogochinskii, A. Z.; Mitrofanov, M. G.; Gavrilova, A.Ye.; Kuprianov, V. A.; Mikhailovskii, V.K.; Vovk, L.M.

doi:10.1016/0031-6458(62)90051-5

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Polymerization Of Benzene By Aluminum Chloride2

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1976

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“…Other catalysts and oxidants are also known to be effective (2)(3)(4). Treatment of benzene with aluminum chloride by prior investigators resulted in the formation of numerous substances including phenylcyclohexane, 1,3-diphenylcyclohexane, 1,4-diphenylcyclohexane, phenylmethylcyclopentane, diphenylmethane, phenol, biphenyl, naphthalene, phenylnaphthalene, anthracene, acenaphthene, and chlorinated products and tars (5)(6)(7). However, poly(p-phenylene) has not been reported as a product of this reaction.…”

Section: Polymerization Of Benzene By Aluminum Chloridementioning

confidence: 99%

“…It is reasonable to assume the existence of increased proportions of 111 and IV in I1 due to the inefficiency of oxidation. Dehydrogenation might be effected either by atmospheric oxygen or disproportionation (5)(6)(7), with cocatalysis of polymerization by adventitious water (1 1,12) or by hydrogen chloride. Structures I11 and IV may also account for the infrared absorption at 1600 cm-' due to carbon-carbon double-bond stretch.…”

Section: Polymerization Of Benzene By Aluminum Chloridementioning

confidence: 99%

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