The homogeneity range of lyonsite-type phase existing in the CrVO4 - Co3V2O8 system

Kurzawa, M.; Bosacka, M.; Filipek, E.; Rychłowska-Himmel, I.

doi:10.2478/s11532-009-0006-2

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“…The two minerals were discovered in the summit crater fumaroles of the Izalco volcano [6,7]. The phases of the structures of lyonsite and howardevansite also form in other analogous ternary systems [8][9][10][11].…”

Section: Introductionmentioning

confidence: 99%

The synthesis and some properties of new compound Cu13Fe4V10O44

Blonska-Tabero

2011

J Therm Anal Calorim

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A new compound with the formula Cu 13 Fe 4 V 10 O 44 has been obtained as a result of a solid-state reactions occurring during heating the mixtures both of oxides: CuO, V 2 O 5 , Fe 2 O 3 and vanadates: Cu 5 V 2 O 10 , Cu 3 Fe 4 V 6 O 24. The DTA measurements were used to choose the heating temperatures as well as for determination of thermal stability of the new compound. Cu 13 Fe 4 V 10 O 44 melts incongruently at 790 ± 5°C. The new phase crystallizes in the monoclinic system. The indexing results and the calculated unit cell parameters for Cu 13 Fe 4 V 10 O 44 are given. Its infra-red spectrum and image obtained by means of an electron scanning microscope are presented.

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Section: Introductionmentioning

confidence: 99%