Prepared porous titanium dioxide film on the titanium matrix by micro-arc oxidation(MAO) method. Using SEM, XPS, XRD, Raman and other testing methods, the titanium dioxide film was characterized. In the ultraviolet radiation, the effect of MAO titanium dioxide film on the degradation rate of Rhodamine B solution was measured, after 180 minutes, 90% Rhodamine B solution was degraded.