Synopsis
The paper presents a review of silica-undersaturated salic intrusions (nenormative trachytes and phonolites) from the Carboniferous-Permian magmatic province in central Scotland. New whole-rock major and trace element analyses, together with Sr and Nd isotopic data, are presented for six intrusions (Bass Rock, North Berwick Law, Traprain Law, Hairy Craig, Fintry and Loudoun Hill) and two syenite autoliths within the Loudoun Hill intrusion.
On the basis of the conventional total alkalis vs. silica diagram, all six intrusions are trachytes except for Traprain Law, which is a phonolite. TraprainLaw is the most highly evolved and the most undersaturated in silica. The Loudoun autoliths are the most basic
IntroductionThe Carboniferous and Permian igneous rocks of central and southern Scotland are predominantly basaltic and range from transitional to mildly alkaline to highly alkaline (Upton et al., 2004). A major suite of tholeiitic basic intrusions that was emplaced during Stephanian time is an exception. The most primitive members of the various suites range from quartz-hypersthene (q-hy)-to hypersthene (hy)-to nepheline (ne)-normative (Macdonald, 1975;Smedley, 1986). During the past thirty years petrological and geochemical attention has primarily been focussed on these more primitive rocks to the near-exclusion of the more-evolved rocks. More-evolved lavas in the range trachybasalt -trachyandesite -trachyte are restricted to the Tournaisian to mid-Visean sequences and there is a close spatial association between these lavas and intrusions of comparable, and even more-evolved, rock-types ( Figure 1). Hence the evolved intrusions have been assumed to be of the same age as the evolved lavas. Younger magmatism (Late Visean to Permian), however, was, with the exception of the Stephanian quartz dolerite event, more magnesian than that of the earlier Carboniferous.Most of the silicic rocks of the province are silica-saturated or over-saturated, defining a trend that leads to quartz-trachyte and, rarely, alkali rhyolite. However, those that are ne-normative (silica-undersaturated) define a separate trend towards phonolite. For those undersaturated compositions that are insufficiently silicadeficient to merit the term phonolite, we use the term phonolitic trachyte. The ne-3 normative cases include several notable intrusions as well as some rare lavas of relatively evolved composition. Deuteric alteration and subsequent weathering commonly make petrographical description of the more-evolved rocks difficult and they commonly contain secondary quartz. Accordingly it is possible that other silicaundersaturated evolved rocks were emplaced but are now unidentifiable.In the previous literature on the central and southern Scottish late Palaeozoic magmatism, the significance and even the existence of these two divergent petrological trends have generally not been recognised, even though they may have important implications for the magma genesis, evolution and age of the intrusions.Here we list all known phonolitic...