An impure-phase GdAlO 3 usually remains in the product of gadolinium aluminum garnet ͑GAG͒ powder as synthesized. In this study, an attempt to prepare a stable GAG pure-phase powder by substituting small cations ͑Tb 3+ , Y 3+ , or Lu 3+ ͒ at the dodecahedral sites or the substituting the large cation ͑Ga 3+ ͒ for the Al 3+ sites of the garnet structure was made. Pure garnet-phase GAG powder was formed by calcining at 1500°C for 2 h. It was found that increasing the Lu 3+ content in the Gd 3+ lattice site of the dodecahedral or increasing the Ga 3+ content in the Al 3+ site induces a blue shift in the emission wavelength. The color temperature of the pure GAG:Ce ͑YAG:Ce͒ phosphor powder ͑ϳ2900 K͒ formed was lower than that of yttrium aluminum garnet and terbium aluminum garnet ͑TAG:Ce͒ phosphors.