The Generation of Neutral Derivatives of Low-Valence Iron, RFe(I), by Netralization—Reionization Mass Spectrometry

Zagorevski, Dmitri V.

doi:10.1255/ejms.743

Cited by 3 publications

References 49 publications

(59 reference statements)

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The Thermochemistry and Energetics of Organoiron Compounds

Liebman

Slayden

2014

Patai's Chemistry of Functional Groups

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The current study concerns the thermochemistry and energetics of organoiron compounds that contain an iron–carbon bond. The main quantities that are discussed are enthalpies of formation and bond energies. The chapter begins with the simplest binary iron carbides and then considers progressively larger neutral and ionic organic ligands. Within the context of small ligands, binding to iron as found in hemes and hemoglobin is discussed. The acidity and basicity of iron‐containing compounds is also included.

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The Thermochemistry and Energetics of Organoiron Compounds

Liebman

Slayden

2014

Patai's Chemistry of Functional Groups

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Gas‐phase Ion Stereochemistry of Iron Complexes probed by Mass Spectrometric Techniques

Palii

2014

Patai's Chemistry of Functional Groups

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Modern mass spectrometry (MS) evolved into a ‘complete chemical laboratory’, enabling studies to be performed on structure and reactivity of ionic species under environment‐free conditions. The advent of theoretical methods as a supplement to experimental MS data has expanded gas‐phase ion chemistry to include the stereochemical perspective. In the last decade IRMPD (infrared multiple‐photon dissociation) and IRSPD (infrared single‐photon dissociation) spectroscopy methods have been increasingly employed to directly probe the 3D structures of mass‐selected ions. This chapter aims to provide an overview (139 references) of gas‐phase ion stereochemistry of metal complexes as exemplified by Fe‐containing species, with a special emphasis on combined experimental/theoretical approaches and the advantages that this prolific partnership brought to the field. A survey of literature has revealed that circa 100 three‐dimensional structures of ionic Fe‐containing species have been characterized to date by both MS techniques and computational methods. These include coordinatively unsaturated organoiron species with various hydrocarbons, Fe complexes with homogeneous and heterogeneous conjugated cyclic hydrocarbons (including PAHs of astrophysical interest), anionic and cationic iron carbonyls, Fe complexes of N‐, O‐ and S‐donor ligands providing classical Werner‐type coordination sites. Some of these gaseous species adopt only a single stable structure, while others generate multiple conformers. In most cases, the reactivity of Fe‐containing species is oxidation‐state dependent. The nature of the ligands in a complex clearly influences the reactivity. With a decrease in the number of available coordination sites on the metal center, the gas‐phase reactivity decreases as well, with a concomitant increase in selectivity.

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Current literature in mass spectrometry

2005

J. Mass Spectrom.

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In order to keep subscribers up‐to‐date with the latest developments in their field, John Wiley & Sons are providing a current awareness service in each issue of the journal. The bibliography contains newly published material in the field of mass spectrometry. Each bibliography is divided into 11 sections: 1 Books, Reviews & Symposia; 2 Instrumental Techniques & Methods; 3 Gas Phase Ion Chemistry; 4 Biology/Biochemistry: Amino Acids, Peptides & Proteins; Carbohydrates; Lipids; Nucleic Acids; 5 Pharmacology/Toxicology; 6 Natural Products; 7 Analysis of Organic Compounds; 8 Analysis of Inorganics/Organometallics; 9 Surface Analysis; 10 Environmental Analysis; 11 Elemental Analysis. Within each section, articles are listed in alphabetical order with respect to author (4 Weeks journals ‐ Search completed at 5th. Oct. 2005)

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The Generation of Neutral Derivatives of Low-Valence Iron, RFe(I), by Netralization—Reionization Mass Spectrometry

Cited by 3 publications

References 49 publications

The Thermochemistry and Energetics of Organoiron Compounds

The Thermochemistry and Energetics of Organoiron Compounds

Gas‐phase Ion Stereochemistry of Iron Complexes probed by Mass Spectrometric Techniques

Current literature in mass spectrometry

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