1959
DOI: 10.2307/3570714
|View full text |Cite
|
Sign up to set email alerts
|

The Gamma Radiolysis of Butyl Chlorides

Abstract: JSTOR is a not-for-profit service that helps scholars, researchers, and students discover, use, and build upon a wide range of content in a trusted digital archive. We use information technology and tools to increase productivity and facilitate new forms of scholarship. For more information about JSTOR, please contact support@jstor.org.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
1

Citation Types

0
2
0

Year Published

1960
1960
2003
2003

Publication Types

Select...
5
2

Relationship

0
7

Authors

Journals

citations
Cited by 13 publications
(2 citation statements)
references
References 8 publications
0
2
0
Order By: Relevance
“…The isomerization of n-propyl chloride by 7-radiolysis (60Co source) is thought to involve the following freeradical mechanisms (189,190), and similarly the forma-CH,CHC1CH2 CH,CHCH2C1 ch,ch2ch2ci + CH,CHC1CH2 -> CH,CHCH2C1 + CH,CHC1CH, tion of sec-and isobutyl chlorides from n-butyl chloride by the action of 7-rays probably occurs with free-radical intermediates (36). Under the influence of n,7 ac-CH,CH2CH2CH2C1 ch,ch2ch2ch2 + 'Cl L rearrangement tivation n-, sec-, iso-, and ¿-butyl bromides all undergo isomerization by bromine shift in addition to other side reactions (124), while both n-and isopropyl bromides isomerize under neutron radiation.…”
Section: Mechchbrmementioning
confidence: 99%
“…The isomerization of n-propyl chloride by 7-radiolysis (60Co source) is thought to involve the following freeradical mechanisms (189,190), and similarly the forma-CH,CHC1CH2 CH,CHCH2C1 ch,ch2ch2ci + CH,CHC1CH2 -> CH,CHCH2C1 + CH,CHC1CH, tion of sec-and isobutyl chlorides from n-butyl chloride by the action of 7-rays probably occurs with free-radical intermediates (36). Under the influence of n,7 ac-CH,CH2CH2CH2C1 ch,ch2ch2ch2 + 'Cl L rearrangement tivation n-, sec-, iso-, and ¿-butyl bromides all undergo isomerization by bromine shift in addition to other side reactions (124), while both n-and isopropyl bromides isomerize under neutron radiation.…”
Section: Mechchbrmementioning
confidence: 99%
“…On the other hand, free-radical rearrangements have been postulated as the explanation for the yinduced isomerization of n-butyl to s-butyl, and i-butyl to t-butyl halides (7,8). The formation of 1-phenylethyl radical in the photolyses of 2-phenylethanol in a rigid medium a t low temperature was suggested as having resulted fro111 isomerization of the 2-phenylethyl radical (5).…”
mentioning
confidence: 99%