The future of polyoxymetalates for biological and chemical apllications

Water-Soluble Polyoxometal Clusters of Molybdenum (V) with Pyrazole and Triazole: Synthesis and Study of Cytotoxicity and Antiviral Activity

“…As was mentioned in the introduction, there are prospects for the use of POMs in the fields of biology and medicine [13,14]. More recent work is also devoted to the study of the biological properties of binuclear molybdenum cluster complexes with organic ligands [28,29].…”

“…In addition to "classical" POMs (such as Lindqvist (Figure 1a), Wells-Dawson, Anderson, etc.-type POMs) [1], hybrid POMs (covalently bonded to organic ligands) [4], POM-based coordination polymers (POMOFs) [5][6][7], various supramolecular assemblies [8][9][10], etc., have been reported in the literature. This diversity of compounds has led to the identification of a number of potentially practical applications for the compounds, mainly in the fields of catalysis [11,12] or biology and medicine [13][14][15][16][17]. In addition to the compounds described above, there are complexes in and medicine [13][14][15][16][17].…”

“…This diversity of compounds has led to the identification of a number of potentially practical applications for the compounds, mainly in the fields of catalysis [11,12] or biology and medicine [13][14][15][16][17]. In addition to the compounds described above, there are complexes in and medicine [13][14][15][16][17]. In addition to the compounds described above, there are complexes in the literature that are structurally similar to POM, but are based on bi-or tri-nuclear molybdenum oxo clusters (Mo V 2O4 and Mo IV 3O4) connected by oxo ligands, organic linkers, or by Mo VI O6-fragements.…”

A dual-heteroatom–lanthanide cluster-embedded polyoxotungstate for sequential fluorescence detection of Fe3+ and pyrophosphate

“…[1][2][3][4][5][6][7][8][9] Heteropolyoxotungstates (HPOTs) are a class of heteroatom (HA)-templated metal oxides and have been extensively applied in luminescence, catalysis, medicine, magnetism, materials science, etc. [10][11][12][13][14][15] Within HPOTs, HA species are wide ranging (from III to VI main groups such as B III , Si IV , Ge IV , P III/V , As III/V , Sb III , Bi III , Se IV and Te IV ), and the combination of diverse HA templates with tungstates leads to a large library of extraordinary HPOTs, [16][17][18][19][20] denoting a versatile subclass of the polyoxometalate (POM) family.…”

Heterointerface Connection with Multiple Hydrogen-Bonding in Z-Scheme Heterojunction SiW9Co3@UiO-67-NH2 Deciding High Stability and Photocatalytic CO2 Reduction Performance

“…However, its high dissolubility often results in the leaching of active components and difficulties in recycling, and meanwhile the narrow bandgap also leads to rapid recombination of electron–hole and limits its photocatalytic application . Compared with the conventional strategy that employing porous materials such as molecular sieves, polymers, or supramolecular cages to simply encapsulate POMs, − the construction of heterojunction photocatalysts by heterogeneous integrating POMs with additional semiconductor components to retard the carrier recombination and immobilize POMs is more highly promising …”