Whereas
bubble growth out of gas-oversatured solutions has been
quite well understood, including the formation and stability of surface
nanobubbles, this is not the case for bubbles forming on catalytic
surfaces due to catalytic reactions, though it has
important implications for gas evolution reactions and self-propulsion
of micro/nanomotors fueled by bubble release. In this work we have
filled this gap by experimentally and theoretically examining the
growth and detachment dynamics of oxygen bubbles from hydrogen peroxide
decomposition catalyzed by gold. We measured the bubble radius R(t) as a function of time by confocal
microscopy and find R(t) ∝ t1/2. This diffusive growth behavior demonstrates
that the bubbles grow from an oxygen-oversaturated environment. For
several consecutive bubbles detaching from the same position in a
short period of time, a well-repeated growing behavior is obtained
from which we conclude the absence of noticeable depletion effect
of oxygen from previous bubbles or increasing oversaturation from
the gas production. In contrast, for two bubbles far apart either
in space or in time, substantial discrepancies in their growth rates
are observed, which we attribute to the variation in the local gas
oversaturation. The current results show that the dynamical evolution
of bubbles is influenced by comprehensive effects combining chemical
catalysis and physical mass transfer. Finally, we find that the size
of the bubbles at the moment of detachment is determined by the balance
between buoyancy and surface tension and by the detailed geometry
at the bubble’s contact line.