The First Disulfur and Diselenium Complexes of Platinum: Syntheses and Crystal Structures

We report the anion [Al(NONAr)(Se)]− (NONAr=[O(SiMe2NAr)2]2−, Ar=2,6‐iPr2C6H3), which is an isoelectronic Group 13 metal analogue of the carbonyl group containing an aluminium–selenium multiple bond. It was synthesized in a single step from the reaction of the aluminyl anion [Al(NONAr)]− with elemental selenium. Spectroscopic, crystallographic, and computational analysis confirmed multiple bonding between aluminium and selenium. Addition of a second equivalent of selenium afforded the diselenirane, [Al(NONAr)(κ2‐Se2)]−, which is an isoelectronic analogue of the dioxirane group.

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Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution

Yao

Xiong

Zhang

et al. 2009

Angew Chem Int Ed

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The First Disulfur and Diselenium Complexes of Platinum: Syntheses and Crystal Structures

Cited by 5 publications

References 54 publications

Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution

Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution

Isoelectronic Aluminium Analogues of Carbonyl and Dioxirane Moieties

Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution

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The First Disulfur and Diselenium Complexes of Platinum: Syntheses and Crystal Structures

Cited by 5 publications

References 54 publications

Facile Dissociation of [(LNiII)2E2] Dichalcogenides: Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution

Facile Dissociation of [(LNiII)2E2] Dichalcogenides: Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution

Isoelectronic Aluminium Analogues of Carbonyl and Dioxirane Moieties

Facile Dissociation of [(LNiII)2E2] Dichalcogenides: Evidence for [LNiIIE2] Superselenides and Supertellurides in Solution

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Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution

Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution

Facile Dissociation of [(LNi^II)₂E₂] Dichalcogenides: Evidence for [LNi^IIE₂] Superselenides and Supertellurides in Solution