The paper focuses on the production of ceramic brick based on aluminum silicate waste generated by thermal power plants. The grain size and chemical compositions of the raw material are investigated. Experimental studies are carried out to identify optimum operating parameters of the ceramic brick production. It is shown that the use of aluminum silicate waste, namely, 40–60 % ash together with clay raw material allows obtaining ceramic brick possessing 20–25 MPa compressive strength, 10–15 % water absorption, and frost resistance of over 60 cycles.