The experimental and modeling study on a new process of iron/cobalt alloy production using indirect reducing agent of glycerol under microwave heating

Shojae, Kianoosh; Khoshandam, Behnam

doi:10.1016/j.cep.2021.108765

Cited by 2 publications

(1 citation statement)

References 29 publications

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“…Processing materials using microwave (MW) energy can offer a wide range of advantages [ 1 , 2 , 3 , 4 ] if it is properly implemented, as compared to other processing techniques. In fact, it had been successfully used to process many materials [ 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 ] in different fields recently, such as but not limited to coal, oxide and carbide ceramics, composites, cement and concrete, alloys, fly ash, and even in CO 2 adsorption. Furthermore, MW energy has been used to heat and to sinter metals and their alloys [ 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 ], from the early reported works where MW was used to heat metals to the most recent reported studies where it has been used to join metals and alloys, but its full use needs a comprehensive understanding of MW–material interactions.…”

Section: Introductionmentioning

confidence: 99%

Characterization of the Native Oxide Shell of Copper Metal Powder Spherical Particles

Mahmoud

2022

Materials

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The native oxide layer that forms on copper (Cu) metal spherical particle surfaces under ambient handling conditions has been shown to have a significant effect on sintering behavior during microwave heating in a previous study, where an abnormal expansion was observed and characterized during sintering of Cu compacts using reducing gases. Because microwave (MW) heating is selective and depends greatly on the dielectric properties of the materials, this thin oxide layer will absorb MW energy easily and can consequently be heated drastically starting from room temperature until the reduction process occurs. In the current study, this oxide ceramic layer was qualitatively and quantitatively characterized using the carrier gas hot extraction (CGHE) method, Auger electron spectroscopy (AES), and a dual-beam focused ion beam (FIB)/scanning electron microscope (SEM) system that combines both FIB and SEM in one single instrument. Two different commercial gas-atomized spherical Cu metal powders with different particle sizes were investigated, where the average oxygen content of the powders was found to be around 0.575 wt% using the CGHE technique. Furthermore, AES spectra along with depth profile measurements were used to qualitatively characterize this oxide layer, with only a rough quantitative thickness approximation due to method limitations and the electron beam reduction effect. For the dual-beam FIB-SEM system, a platinum (Pt) coating was first deposited on the Cu particle surfaces prior to any characterization in order to protect and to preserve the oxide layer from any possible beam-induced reduction. Subsequently, the Pt-coated Cu particles were then cross-sectioned in the middle in situ using an FIB beam, where SEM micrographs of the resulted fresh sections were characterized at a 36° angle stage tilt with four different detector modes. Quantitative thickness characterization of this native oxide layer was successfully achieved using the adapted dual-beam FIB-SEM setup with more accuracy. Overall, the native Cu oxide layer was found to be inhomogeneous over the particles, and its thickness was strongly dependent on particle size. The thickness ranged from around 22–67 nm for Cu powder with a 10 µm average particle size (APS) and around 850–1050 nm for one with less than 149 µm.

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Section: Introductionmentioning

confidence: 99%

Characterization of the Native Oxide Shell of Copper Metal Powder Spherical Particles

Mahmoud

2022

Materials

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The synthesis of cobalt nanoparticles by solution combustion synthesis method in a new reactor at low-temperature conditions

Barati,

Khoshandam

2023

Proceedings of the Institution of Mechanical Engineers, Part N:

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The novelty of the present paper was the construction of a new reactor to synthesize the cobalt nanoparticles (NPs) by solution combustion synthesis (SCS) method for reducing the processing temperature of cobalt production. To perform the SCS process, a reactor was designed and constructed and the synthesis process was performed using cobalt (II) nitrate-6-water as oxidizer along with glycine and urea as fuels. The effect of the molar ratio of glycine fuel to oxidizer and fuel type parameters on the purity of the products were examined. The XRD and FESEM analysis were used to characterize the obtained products. Based on FESEM analysis and the Scherrer equation, the mean size of all samples was under 100 nm and the reactor loaded with the glycine fuel provided the lowest particle sizes by around 14 nm and produced particles with better surface adhesion. It was found that the glycine fuel was determined the best fuel compared to urea because of producing temperatures near 400°C. Compared to traditional gas-solid reactions, the operating temperature of this process was under 400°C which was considerably lower than the operating temperature of gas-solid reactions occurred at temperatures higher than 800°C.

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The experimental and modeling study on a new process of iron/cobalt alloy production using indirect reducing agent of glycerol under microwave heating

Cited by 2 publications

References 29 publications

Characterization of the Native Oxide Shell of Copper Metal Powder Spherical Particles

Characterization of the Native Oxide Shell of Copper Metal Powder Spherical Particles

The synthesis of cobalt nanoparticles by solution combustion synthesis method in a new reactor at low-temperature conditions

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