Abstract. Since the Quaternary Period, paleo-seawater intrusions have been suggested
to explain the observed saline groundwater that extends far inland in
coastal zones. The Luanhe River delta (northwest coast of the Bohai Sea, China)
is characterized by the distribution of saline, brine, brackish, and fresh
groundwater from the coastline inland. The groundwater in this region exhibits a wide range of total dissolved
solids (TDS): 0.38–125.9 g L−1. Meanwhile, previous studies have
revealed that this area was significantly affected by Holocene marine
transgression. This study used hydrochemical, isotopic, and sedimentological
methods to investigate groundwater salinization processes in the Luanhe
River delta and its links to paleo-environmental settings. Isotopic
results (2H, 18O, 14C) allowed old groundwater recharge to be distinguished from
new groundwater recharge. Hydrochemical analysis using the PHREEQC code
indicated that the salt in saline and brine groundwater originates from a
marine source. The 18O–Cl relationship diagram yields three-end-member
groundwater mixing, and two mixing scenarios are suggested to explain the
freshening and salinization processes in the study area. When this was interpreted
along with data from paleo-environmental sediments, we found that groundwater
salinization may have occurred since the Holocene marine transgression. The
brine is characterized by radiocarbon activities of ∼ 50–85 pMC and relatively depleted stable isotopes, which are associated with
seawater evaporation in the ancient lagoon during delta progradation and
mixing with deeper fresh groundwater, which was probably recharged in the cold
Late Pleistocene. The brackish and fresh groundwaters are
characterized by river-like stable isotope values, where high radiocarbon
activities (74.3–105.9 pMC) were formed after the washing out of the salinized
aquifer by surface water in the delta plain. This study presents an approach
that utilizes geochemical indicator analysis with paleo-geographic
reconstruction to better assess groundwater evolutionary patterns in coastal
aquifers.