Abstract:The molecular-orbital method has been applied to a study of in its ground state and excited levels, and the relative importance of the perturbation and variational methods has been considered in some detail, as well as the effect of certain integrals which, in discussions of molecular structure, have often been neglected. It appears that the ion should exist in stable equilateral form with a nuclear distance about 0·85 Å., and that all excited levels are unstable.Reasons are given for supposing that the mole… Show more
“…This is consistent with a covalently bound trimer in which the unpaired electron resides in an antibonding orbital with a node at one alkali centre but has some spin density on the central atom due to polarization. Such a description is analogous to the molecular orbital picture for H, [22]. The spectra are also consistent with an ionic charge-transfer model corresponding to M~+M-or "M2-M+ , in which the odd electron resides largely on the dialkali cation or anion.…”
E.S.R. spectra assigned to Na3 molecules have been obtained by codepositing sodium atoms and diluent argon on a sapphire surface loosely coupled to a liquid helium cryostat and warmed by a heat leak, to allow aggregation before the alkali atoms are frozen into the argon matrix. The trimer spectra under these conditions were much more intense than the residual atom spectra. The trimer spectra indicate the unpaired electron in these molecules has predominantly s rather than p character. Approximately 95 per cent of the 3s spin density is equally distributed between two of the alkali atoms, with 0nly about 7 per cent of the spin density on the third atom. The trimers thus are not merely van der Waals adducts but involve chemical bonding. Both a covalent molecular orbital model for linear or obtuse isosceles geometry and an ionic charge-transfer model giving M2+M -or M+M2 -appear qualitatively consistent with the spectra.
“…This is consistent with a covalently bound trimer in which the unpaired electron resides in an antibonding orbital with a node at one alkali centre but has some spin density on the central atom due to polarization. Such a description is analogous to the molecular orbital picture for H, [22]. The spectra are also consistent with an ionic charge-transfer model corresponding to M~+M-or "M2-M+ , in which the odd electron resides largely on the dialkali cation or anion.…”
E.S.R. spectra assigned to Na3 molecules have been obtained by codepositing sodium atoms and diluent argon on a sapphire surface loosely coupled to a liquid helium cryostat and warmed by a heat leak, to allow aggregation before the alkali atoms are frozen into the argon matrix. The trimer spectra under these conditions were much more intense than the residual atom spectra. The trimer spectra indicate the unpaired electron in these molecules has predominantly s rather than p character. Approximately 95 per cent of the 3s spin density is equally distributed between two of the alkali atoms, with 0nly about 7 per cent of the spin density on the third atom. The trimers thus are not merely van der Waals adducts but involve chemical bonding. Both a covalent molecular orbital model for linear or obtuse isosceles geometry and an ionic charge-transfer model giving M2+M -or M+M2 -appear qualitatively consistent with the spectra.
“…After its discovery by J.J. Thomson in 1911 [8], the divalent nature of bonding was a mystery to authors of early theoretical papers including illustrious names such as Bohr [9], Massey [10], Hirschfelder [11][12][13][14][15], and Eyring [12,13]. With Lennard-Jones's suggestion, Coulson [16] applied the molecular orbital method to H þ 3 and concluded that its equilibrium structure is an equilateral triangle although the calculation was severely criticized [12]. These pioneering papers were followed by a great many theoretical works especially after the advent of modern computers (see Oka [17], McNab [18] and Anderson [19] for review).…”
“…Its exceptional importance in astrophysics related to interstellar media explains the great interest in this ion from astronomy, astrophysics and chemistry communities (for a detailed review, see, [7]). For all these reasons, there have been extensive theoretical and experimental works on this molecular ion since the pioneering (semi-quantitative) work by Coulson [8].…”
A first detailed study of the ground state of the H + 3 molecular ion in linear configuration, parallel to a magnetic field direction, and its low-lying Σ, Π, ∆ states is carried out for magnetic fields
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