The electrochemical applications of rare earth-based nanomaterials

Huang, Haiping; Zhu, Jun‐Jie

doi:10.1039/c9an01562k

Cited by 72 publications

(38 citation statements)

References 116 publications

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“…These nanoparticles can carry our different functions in sensors, e.g., transduction element, amplier to enhance chemical and electrochemical signals, catalyst and nanozyme that can replace biological enzymes, and label in bio-affinity assays. 88,89 Electrochemical behavior of ceria and nanoceria depend on their morphologies affected by the growth rates of ceria nanocrystalline relied on solvent composition. Furthermore, shiing between oxidation states of Ce 3+ and Ce 4+ enhances electrochemical property of nanoceria.…”

Section: Applications Of Nanoceria In Electrochemical Sensorsmentioning

confidence: 99%

“…In most cases, the presence of ceria increase the surface area, i.e., more nanoparticles could attach to the surface which enhances the direct electron transfer rate. 89 For example in one study using nanoceria, a non-enzymatic sensor for monitoring glucose was developed. The combination of nanoceria and gold nanoparticles (AuNPs) on glassy carbon electrodes (GCE) enhanced the enzyme-electron transfer, and increased the electron transfer rate.…”

Section: Electrochemical Sensormentioning

confidence: 99%

“…Using this method, direct measurement of H 2 O 2 could be used to detect, quantify, and diagnose pathological conditions, e.g., infection and inammation. 89 Modied GCE via nanohybrid of single-walled carbon nanohorns (SWCNHs) enveloped with CeO 2 in a coreshell hierarchy was successfully applied as an electrochemical sensor. Ink-like suspensions of SWCNHs@CeO 2 were cast on the clean GCE surface, and dried in the oven.…”

Section: Electrochemical Sensormentioning

confidence: 99%

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Synthesis and characterization of nanoceria for electrochemical sensing applications

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Section: Applications Of Nanoceria In Electrochemical Sensorsmentioning

confidence: 99%

Section: Electrochemical Sensormentioning

confidence: 99%

Section: Electrochemical Sensormentioning

confidence: 99%

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Synthesis and characterization of nanoceria for electrochemical sensing applications

et al. 2021

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“…Rare earth elements, known as "industrial vitamins", are widely used in catalysts, permanent magnets, glassmaking, lighting and other fields (Huang and Zhu 2019;Liang et al 2018;Ni'am et al 2020;Zhao et al 2019). Dysprosium (Dy) has always been one of the most important rare earth elements because of its irreplaceable role in optics and permanent magnets (Bisaka et al 2017;Fujiwara et al 2016;Liang et al 2018;Zheng et al 2020).…”

Section: Introductionmentioning

confidence: 99%

Graphene Oxide and Polyethyleneimine Cooperative Construct Ionic Imprinted Cellulose Nanocrystals Aerogel for Selective Adsorption of Dy(III)

Zheng

Sun

et al. 2021

Preprint

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Because of dysprosium's unique physical and chemical properties and limited supply, the price of rare earth dysprosium has been high in recent years. Therefore, the study of the method of high efficiency selective separation of dysprosium has the double value of scientific research and practical economy. In this paper, we used periodic cellulose nanocrystals as the basic structure, polyethylenimine and graphene oxide were introduced, combined with imprinting technology, to construct porous imprinted aerogel and use it for selective adsorption of Dy(III). The physical and chemical properties were characterized by SEM, TEM, FT-IR and TGA. It was proved that both polyethylenimine and graphene oxide were crosslinked effectively with cellulose nanocrystals. Adsorption experiments showed that the composite imprinted aerogel could selectively adsorb dysprosium effectively, and the maximum adsorption capacity for Dy(III) was 39.027 mg g− 1. The reproducibility experiment showed that aerogel had good regeneration ability. In conclusion, cellulose nanocrystals aerogel, which is environmentally friendly, efficient and repeatable, is expected to provide a new direction for the recovery of rare earth elements.

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“…[1,2]. Среди них халькогениды РЗЭ, обладающие высокой термостойкостью, устойчивостью к резким изменениям условий окружающей среды, уникальными магнитными, оптическими и термоэлектрическими свойствами, нашли свое применение в современной электронной технике [3][4][5][6][7][8][9][10].…”

Section: Introductionunclassified

Thermodynamic Properties of Terbium Tellurides

Imamaliyeva

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Зломанов

et al. 2020

kcmf

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The paper presents the results of a study of solid-phase equilibria in the Tb–Te system and the thermodynamic properties of terbium tellurides obtained by the methods of electromotive forces and X-ray diffraction analysis. Based on the experimental data, it was established that the TbTe, Tb2Te3, TbTe2 и TbTe3 compounds are formed in the system. For the investigations of the alloys from the two-phase regions TbTe3+Te, TbTe2+TbTe3, and Tb2Te3+TbTe2, the EMF of concentration cells relative to the TbTe electrode was measured. The EMF of concentration cells relative to the terbium electrode was measured for the TbTe+Tb2T3 region. The partial thermodynamic functions of TbTe and Tb in alloys were determined bycombining the EMF measurements of both types in the 300–450 K temperature range, based on which the standard thermodynamic functions of formation and standard entropies of the indicated terbium tellurides were calculated. References1. Jha A. R. Rare earth materials: properties andapplications. United States. CRC Press. 2014. 371 p.DOI: https://doi.org/10.1201/b170452. Balaram V. Rare earth elements: A review ofapplications, occurrence, exploration, analysis,recycling, and environmental impact. GeoscienceFrontiers. 2019;10(4): 1285–1290. DOI: https://doi.org/10.1016/j.gsf.2018.12.0053. Yarembash E. I., Eliseev A. A. Khal’kogenidyredkozemel’nykh elementov [Chalcogenides of rareearth elements). Moscow: Nauka Publ.; 1975. 258p.(In Russ.)4. Y-Sc., La-Lu. Gmelin Handbock of InorganicChemistry. In: Hartmut Bergmann (Ed.), Rare EarthElements, 8th Edition, Springer-Verlag HeidelbergGmbH. Berlin; 1987.5. Muthuselvam I. P., Nehru R., Babu K. R.,Saranya K., Kaul S. N., Chen S-M, Chen W-T, Liu Y.,Guo G-Y, Xiu F., Sankar R. Gd2Te3 an antiferromagneticsemimetal. J. Condens. Matter Phys. 2019;31(28):285802-5. DOI: https://doi.org/10.1088/1361-648X/ab15706. Huang H., Zhu J.-J. The electrochemicalapplications of rare earth-based nanomaterials.Analyst. 2019;144(23): 6789–6811. DOI: https://doi.org/10.1039/C9AN01562K7. Saint-Paul M., Monceau P. Survey of thethermodynamic properties of the charge density wavesystems. Adv. Cond. Matter Phys. 2019: 1–5 DOI:https://doi.org/10.1155/2019/21382648. Cheikh D., Hogan B. E., Vo T., Allmen P. V., Lee K.,Smiadak D. M., Zevalkink A., Dunn B. S., Fleurial J-P.,Bux S. L. Praseodymium telluride: A high temperature,high- ZT thermoelectric material. Joule. 2018; 2(4):698–709. DOI: https://doi.org/10.1016/j.joule.2018.01.0139. Patil S. J., Lokhande A. C., Lee D. W, Kim J. H.,Lokhande C. D. Chemical synthesis and supercapacitiveproperties of lanthanum telluride thin film. Journal ofColloid and Interface Science. 2017; 490: 147–153. DOI:https://doi.org/10.1016/j.jcis.2016.11.02010. Zhou X. Z., Zhng K. H. L, Xiog J., Park J-H,Dickerson J-H., He W. 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Binary alloys phase diagrams,second edition. ASM International, Materials Park.Ohio; 1990. 3835 p. DOI: https://doi.org/10.1002/adma.1991003121515. Diagrammi sostoyaniya dvoynikh metallicheskikhsystem [Diagrams of Binary Metallic Systems]Handbook in 3 vols. Lyakishev N.P. (Ed.) Moscow:Mashinostroenie Publ.; 1996, 1997, 2001. (In Russ.)16. Eliseev A. A., Orlova I. G., Martynova L. F.,Pechennikov A. V., Chechernikov V. I. Paramagnetismof some terbium chalcogenides. Inorganic Materials.1987;23: 1833–1835.17. Mills K. C. Thermodynamic data for inorganicsulphides, selenides, and tellurides. London:Butterworth; 1974. 854 p.18. Vassiliev V. P., Lysenko V. A. Gaune-Escard M.Relationship of thermodynamic data with periodic law.Pure and Applied Chemistry. 2019;91(6): 879–884. DOI:https://doi.org/10.1515/pac-2018-071719. Vassiliev V. P., Lysenko V. A. New approach forthe study of thermodynamic properties of lanthanidecompounds. Electrochimica Acta. 2016;222: 1770–1775.DOI: https://doi.org/10.1016/j.electacta.2016.11.07520. Morachevsky A. G., Voronin G. F., Geyderich V. A.,Kutsenok I. B. Elektrokhimicheskie metody issledovaniyav t e r m o d i n a m i k e m e t a l l i c h e s k i k h s y s t e m .[Electrochemical methods of investigation inhermodynamics of metal systems]. Moscow:Akademkniga Publ.; 2003. 334 p. Available at: https://elibrary.ru/item.asp?id=19603291 (In Russ.)21. Babanly M. B., Yusibov Y. A. Elektrokhimicheskiemetody v termodinamike neorganicheskikh sistem[Electrochemical methods in thermodynamics ofinorganic systems]. Baku: BSU Publ.; 2011. 306 p.22. Imamaliyeva S. Z., Mehdiyeva I. F., Taghiyev D. B.et al. Thermodynamic investigations of the erbiumtellurides by EMF method. Physics and Chemistry ofSolid State. 2020;21(2): 312–318. DOI: https://doi.org/10.15330/pcss.21.2.312-31823. Hasanova G. S., Aghazade A. I., Yusibov Yu. A.,Babanly M. B. Thermodynamic investigation of theBi2Se3-Bi2Te3 system by the EMF method. Kondensirovannyesredy i mezhfaznye granitsy = CondensedMatter and Interphases. 2020;22(3): 310–319. DOI:https://doi.org/10.17308/kcmf.2020.22/296124. Imamaliyeva S. Z., Babanly D. M., Gasanly T. M.,et al.: Thermodynamic properties of Tl9GdTe6 andTlGdTe2. Russian Journal of Physical Chemistry A.2018;92(11): 2111–2116. DOI: https://doi.org/10.1134/s003602441811015825. Mansimova S. H., Orujlu E. N., Sultanova S. G.,Babanly M. B. Thermodynamic properties of Pb6Sb6Se17.Kondensirovannye sredy i mezhfaznye granitsy =Condensed Matter and Interphases. 2017;19(4): 536–541. https://doi.org/10.17308/kcmf.2017.19/23426. Imamaliyeva S. Z., Gasanly T. M., MahmudovaM. A. Thermodynamic properties of GdTe compound.Physics. 2017;22: 19–21. Available at: http://physics.gov.az/Dom/2017/AJP_Fizika_04_2017_en.pdf27. Imamaliyeva S. Z., Musayeva S. S., Babanly D. M.,Jafarov Y. I., Tagiyev D. B., Babanly M. B. Determinationof the thermodynamic functions of bismuthchalcoiodides by EMF method with morpholiniumformate as electrolyte. Thermochim. Acta. 2019; 679:178319–17825. DOI: https://doi.org/10.1016/j.tca.2019.17831928. Baza dannykh termicheskikh konstant veshchestv.Elektronnaya versiya pod. red. V. S. Yungmana. 2006[Database of thermal constants of substances.Electronic version V. S. Yungman (ed.). 2006]. Availableat: http://www.chem.msu.ru/cgi-bin/tkv.pl?show=welcome.html/welcome.html

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The electrochemical applications of rare earth-based nanomaterials

Abstract: This review presents a general description of the synthesis and electrochemical properties of rare earth-based nanomaterials and their electrochemical applications.

Cited by 72 publications

References 116 publications

Synthesis and characterization of nanoceria for electrochemical sensing applications

Synthesis and characterization of nanoceria for electrochemical sensing applications

Graphene Oxide and Polyethyleneimine Cooperative Construct Ionic Imprinted Cellulose Nanocrystals Aerogel for Selective Adsorption of Dy(III)

Thermodynamic Properties of Terbium Tellurides

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