SynopsisFrom thermodynamic considerations based on associated solution models and from the Hansen's three-dimensional solubility parameter concept, it is found that the solvent power of an organic liquid for a given polymer can be characterized by two parameters, 8,, and xH, where 6, is the hydrogen-bonding solubility parameter of the liquid, and xH is a term which takes account of the dispersion and polar interactions between the liquid and the polymer and of the effects due to temperature and molecular size of the liquid. It is also found that Hansen's solubility sphere for the polymer can be represented as a solubility circle in the proposed X K~, , plane. The proposed approach is applied ~uccess-fully t o polymer-plasticizer systems.