“…Previous studies have successfully used XRF analysis to identify marine indicators in coastal sediments, e.g., chlorine (Cl), calcium (Ca), strontium (Sr), and zirconium (Zr) (Ercolani et al, 2015;Liu et al, 2014;McCloskey et al, 2018aMcCloskey et al, , 2018bRamírez-Herrera et al, 2012;Yao et al, 2019Yao et al, , 2020, as well as terrestrial runoff (e.g., iron (Fe), titanium (Ti), and potassium (K) in sedimentary records (Haug et al, 2001;van Soelen et al, 2012;You, 2008). In particular, the chlorine/bromine (Cl/Br) ratio has been used as a marine indicator in sediment-stratigraphic studies in coastal and estuarine environments (Liu et al, 2014;McCloskey et al, 2018aMcCloskey et al, , 2018bYao et al, , 2019Yao et al, , 2020. When a solid or liquid sample is excited by a primary X-ray source, elements present in the sample produce a fluorescent X-ray that is unique for that specific element.…”