In this work, gas tungsten arc welding (GTAW) was used to repair ZG06Cr13Ni4Mo martensitic stainless steel. Repair welding occurred either once or twice. The changes in the microstructure and properties of the repair welded joints were characterized by optical microscope (OM), scanning electron microscope (SEM), electron backscattering diffraction (EBSD), tensile and impact tests. The effects of reversed austenite in repair welded joints on microstructure and mechanical properties were studied. The results show that the microstructure of the welded joint after repair welding consists of a large amount of martensite (M) and a small amount of reversed austenite (A), and the reversed austenite is distributed at the boundary of martensite lath in fine strips. With the increase in the number of welding repairs, the content of reversed austenite in the welded joint increases. The microstructure in the repair welded joints is gradually refined, the microstructure in the once and twice repaired joints is 45.2% and 65.1% finer than that in the casting base metal, respectively. The reversed austenite presented in the repair welded joints decreases the tensile strength by 4.8% and 6.7%, increases the yield strength by 21.3% and 26.4%, and increases the elongation by 25% and 56%, respectively, compared with the casting base metal. In addition, the reversed austenite mainly nucleates and grows at the boundary of lath martensite. The refinement of the martensite structure was due to the generation of reversed austenite and the refinement of original austenite grain by the welding thermal cycle. After repair welding, the reverse austenite appeared in the repair welded joints and the tensile strength decreased slightly, but the plastic toughness was significantly improved, which was conducive to the subsequent service process.