Attentional properties are an important component of the success of the sporting activity of the shooting athlete. Scientific works present the results of the development of athletes’ attentional abilities. However, studies concerning the development of attention characteristics specifically in shooting athletes are very scarce. Besides, effective programs of complex training work on the psychological preparation of an athlete, based on multifunctional approaches aimed at the development of the cognitive sphere of a shooter’s personality, are insufficiently described. The aim of the article is to study the possibilities of psychological training as a method of developing attentional characteristics in high-class athletes in rifle shooting and clay target shooting. Twenty-seven shooting athletes of the Klimenko School of Olympic Reserve in Shooting (Simferopol) took part in the formative experiment. Diagnostic study was based on the following methods: B. Bourdon’s proof test, Schulte tables, Gorbov-Schulte tables, H. Münsterberg test. To analyze the differences in the athletes’ attention characteristics before and after the training program implementation the nonparametric Fisher’s criterion and the Wilcoxon’s criterion methods of mathematical statistics were used. Verification of differences in attentional characteristics of athletes before and after the implementation of training allowed obtaining statistically significant differences in the following characteristics of attention: the number of athletes with a high level of attention concentration increased (φe=1.723, р≤0.05); the scope of attention increased (Temp = 26.5, р≤0.001) and the percentage of athletes with a sufficient rate of sensorimotor reactions increased (φe=1.928, р≤0.05); the proportion of athletes with above-average and high levels of attention switching increased (φe=1.645*, р≤0.05); the level of attention selectivity increased (Тemp=23, р≤0.005). Changes in attention indicators of athletes before and after training showed the effectiveness of the training program. Thus, one of the perspective directions of increase of attentional characteristics of athletes in rifle shooting and clay target shooting is introduction of attention development to the process of preparation of psychological training which allows improving cognitive, operational new formations, giving the chance to the sportsman to show high level of concentration, the ability to switch attention, scope and stability of attention in a difficult situation of preparation and competition.