The effects of different dimensional organic amines on synthetic zinc phosphites/phosphates

Wang, Xuelei; Zhou, Yue; Dong, Zhaojun; Meng, Chao; Li, Xiang; Hong, Xiaodong; Yang, Shaobin

doi:10.1007/s10934-019-00790-2

Cited by 3 publications

(3 citation statements)

References 44 publications

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“…Additionally, the simulated and experimental XRD data of three metal-containing zinc phosphate molecular sieves were tested. It can be found that the XRD data obtained from three experiments of metal-containing zinc phosphate have a good agreement with the simulation of [C 6 H 14 N 2 ][Zn 2 (PO 4 ) 2 ] EDI zeolite (Figure 4) [24]. The crystal data are as follows: Tetragonal crystal system, P-42 1 c space group, a = b = 9.9611(8) Å, c = 12.800(2) Å, α = β = γ = 90.00 • .…”

Section: Synthesis and Characterizationsupporting

confidence: 69%

“…The gel was put into the 50 mL reactor as fast as possible and heated for 72 h at 160 • C to obtain the target product (1) molecular sieve. Compared with conventional hydrothermal synthesis [24], products prepared by sol-gel assisted hydrothermal synthesis have perfect shape and were prepared at lower heat treatment temperature. The final products were rinsed twice with demineralized water and dried in the air.…”

Section: Synthesismentioning

confidence: 99%

“…Advance to the present, zinc phosphate molecular sieves contain multiple topologies [23]. Among them, zinc phosphate ([C 6 H 14 N 2 ][Zn 2 (PO 4 ) 2 ]) with the edingtonite framework topology structure is reported by our research group [24]. In order to extend the performance and application of these zinc phosphate molecular sieves, many studies have been done on metal substitution of zinc phosphate zeolites [25][26][27][28][29][30].…”

Section: Introductionmentioning

confidence: 99%

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Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method

et al. 2020

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Three different metal-containing zinc phosphate, [C3H12N2][Zn0.5Fe1.5(PO4)2] (1), [C3H12N2][Zn0.67Co1.33(PO4)2] (2) and [C3H12N2][Zn0.67Ni1.33(PO4)2] (3) with EDI topology were prepared by sol–gel assisted hydrothermal method. The advantages of this method are lower synthesis temperature and uniform mixing. The crystalline metal-containing zinc phosphate zeolites exhibit a variety of SEM morphologies because of the entanglement of three different metal ions. The zinc ions in the zinc phosphate EDI molecular sieve were partially substituted by Fe, Co and Ni ions. The ICP analysis shows that the metal ratios of Zn/M are 1/3, 1/2 and 1/2. Variable temperature susceptibility was measured on powder samples in the range 2–300 K. All three M-EDI molecular sieves exhibit antiferromagnetic properties. In addition, they were analyzed by XRD, CHN, IR and TG.

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Section: Synthesis and Characterizationsupporting

confidence: 69%

Section: Synthesismentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method

et al. 2020

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A reactive compatibilization with the compound containing four epoxy groups for polylactic acid/poly(butylene adipate-co-terephthalate)/thermoplastic starch ternary bio-composites

Fang,

Lin,

Zhang

et al. 2024

International Journal of Biological Macromolecules

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The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates

et al. 2020

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Four metal phosphites/phosphates crystal materials C8N4H34Al2P4O18 (1), C3N2H17GaP2O8 (2), H5In2P3O10 (3), and H9In2P3O13 (4) have been solvothermally synthesized by organic amines in the presence of mixed solvents. Structural analyses indicate that compound 1 and 2 show one-dimensional (1D) chain structures; compound 3 and 4 are three-dimensional (3D) inorganic open-framework indium phosphites. Organic amines show different mechanisms in the four compounds. The 2,2′-bipyridine organic amine acts as a template source and it breaks down small molecules, which enter into the structure of compound 1. For compound 2, 1,2-propanediamine has a role as protonated template and it forms a hydrogen bond with the inorganic skeleton structure. As for compound 3 and 4 without the organic template, the benzylamine and 2,2′-bipyridine mainly serve as structure-directing agent. Especially, compound 3 has an odd seven-ring channel, and compound 4 contains 3D intersecting six-ring, eight-ring, and 10-ring channels. X-ray diffraction (XRD), scanning electron microscopy (SEM), CHN, inductive coupled plasma (ICP), Infrared (IR), and thermal gravimetric (TG) analyze the four compounds.

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The effects of different dimensional organic amines on synthetic zinc phosphites/phosphates

Cited by 3 publications

References 44 publications

Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method

Metal-Containing Zinc Phosphate EDI Zeolites Synthesized by Sol–gel Assisted Hydrothermal Method

A reactive compatibilization with the compound containing four epoxy groups for polylactic acid/poly(butylene adipate-co-terephthalate)/thermoplastic starch ternary bio-composites

The Different Effects of Organic Amines on Synthetic Metal Phosphites/Phosphates

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