The Effect of α-Al2O3 Composite on Energy Storage Characteristics of the Orthogonal Phase PLZST Antiferroelectric Ceramics

Abstract

The effect of (1-x)(Pb0.97La0.02)(Zr0.675Sn0.285Ti0.04)O3-xAl2O3, with x=0~0.04, 0.08, 0.10 composite ceramic samples was studied. In this experiment, the PLZST powder was pre-fired to obtain the perovskite structure, and then combined with α-Al2O3 to increase the BDS of the ceramic. The test results show that the composite thick film samples are all perovskite orthorhombic phases, and Al2O3 is mainly filled in the grain gaps with a flaky structure. A proper content of composite Al2O3 can increase the density of ceramics. With x=0.02, the maximum value of BDS is 25.27 kV/mm, which is 60% higher than pure PLZST material, and the releasable energy storage density also reaches a maximum of 2.95 J/cm³. After the composite amount exceeds 0.03, the saturation polarization intensity decreases significantly. The energy storage efficiency of each sample is generally not high, all of which are less than 65%.