A comparative investigation of -phase transformation in base and modified experimental alloy RR2072 (C, Hf, and B) has been undertaken. The alloys were exposed at 950 ЊC for 5 to 500 hours. It was found that -phase transformation was notably retarded in the modified alloys due to the prior formation of M 23 C 6 carbides and Ta/Ti being tied up in the MC phase. Detailed investigation has revealed that M 23 C 6 carbides absorb Cr, Mo, and Co, consequently retarding -phase transformation that demands Cr, Mo, and Co in addition to Re. In the interdendritic regions, the growth of -phase was physically limited by MC carbides and chemically inhibited by the very localized microsegregation.