The Effect of the Solvent on the Polarographic Reduction of Cations<sup>1</sup>

Bruss, D. B.; Vries, Thomas De

doi:10.1021/ja01585a012

Cited by 44 publications

(9 citation statements)

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“…Bruss and DeVries (7) in a study of the effect of solvents on the polarographic reduction of cations observed the E,~ values of bismuth, cadmium, chromium (III), and zinc ions against a silver-silver chloride electrode in a number of different solvents of which formamide was one. Their values for cadmium and zinc ions check with ours when one considers the different reference electrodes used.…”

mentioning

confidence: 99%

Polarography in Formamide

Brown¹,

Hsiung²

1960

J. Electrochem. Soc.

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confidence: 99%

Polarography in Formamide

Brown¹,

Hsiung²

1960

J. Electrochem. Soc.

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“…Example extrapolation for determination of the static dielectric constant (ε s ) with formamide (F). Literature values for static permittivity are shown as crosses. ,– …”

Section: Experimental Methodsmentioning

confidence: 99%

“…All measurements were performed at 298 K, unless otherwise stated. ε s and ε ∞ literature values for F, ,,– NMF ,,,,,,,– , and NEF. – …”

Section: Experimental Methodsmentioning

confidence: 99%

Correlation of Dielectric Properties with Structure and H-Bonding for Liquids

Bennett,

Calisir,

Yang

et al. 2023

J. Phys. Chem. C

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A study focused on the correlation among dielectric properties, molecular structure, and H-bonding is presented using liquid formamides with increasing carbon chain lengths as a model series. 1 H NMR is used to determine the extent of H-bonding via Abraham solute hydrogen bond acidity parameter, A. The results show a clear quantitative correlation, with higher A linked with increased relaxation times (τ) and a drop in the static dielectric constants (ε s ), with differences between the 1 and 2°amides observed. Overall, the findings advance our understanding of the intricate relationship between dielectric properties and H-bonding, with potential applications toward the design of materials exhibiting tailored dielectric properties and the study of amide-containing molecules (such as DNA, peptides, proteins, and nylon polymers) and other liquids which may associate via H-bonding.

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“…In the case of MnCl 2 , the polarographic wave is usually not observed in DMF solutions. 10 The polymerization degree of poly-VBI ⅐ NiCl 2 was evaluated by viscometry (propyl alcohol, 293 K, ␣ ϭ 0.70, K ϭ 0.75 ϫ 10 Ϫ4 ; ref. 11) after desorption of NiCl 2 .…”

Section: Experimental and Calculationsmentioning

confidence: 99%

Complexes of 1-vinylazoles with transition metals in radical polymerization

Danilovtseva

Annenkov

Skushnikova

et al. 2000

J. Appl. Polym. Sci.

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Radical polymerization of the complexes of 1‐vinylimidazole, 1‐vinylbenzimidazole, and 1‐vinylbenztriazole with MnCl2, NiCl2, and ZnCl2 was investigated. It was found that the polymerization is accompanied by spontaneous polymerization in the case of MnCl2 and ZnCl2, inhibition by coordination of macroradicals with Ni2+ ions, and a gel effect by crosslinking of the formed polymer during the complexing with Zn2+. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 101–108, 2000

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The Effect of the Solvent on the Polarographic Reduction of Cations¹

Cited by 44 publications

References 0 publications

Polarography in Formamide

Polarography in Formamide

Correlation of Dielectric Properties with Structure and H-Bonding for Liquids

Complexes of 1-vinylazoles with transition metals in radical polymerization

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The Effect of the Solvent on the Polarographic Reduction of Cations1

Cited by 44 publications

References 0 publications

Polarography in Formamide

Polarography in Formamide

Correlation of Dielectric Properties with Structure and H-Bonding for Liquids

Complexes of 1-vinylazoles with transition metals in radical polymerization

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The Effect of the Solvent on the Polarographic Reduction of Cations¹