Cadmium sulfide CdS has band gab of 2.42 eV, which is suitable as window material for thin film to fabricate solar cell. It has high absorption coefficient and acceptable conversion efficiency in addition to its low cost. Many samples are prepared using vacuum evaporation techniques with different deposition parameters. Hall Effect, resistivity and optoelectronic measurements are conducted on the fabricated samples. The analysis of the results indicates that the optoelectronic properties, namely photogenerated current are dependent on the thickness, substrate temperature and deposition rate.