Abstract:Observations are reported on linear low-density polyethylene in isothermal torsional oscillation and relaxation tests at various temperatures ranging from room temperature to 110 C. Constitutive equations are derived for the viscoelastic response of a semicrystalline polymer at small strains. The polymer is treated as an equivalent network of strands bridged by junctions (entanglements, physical cross-links on the surfaces of crystallites and lamellar blocks). The network is thought of as an ensemble of meso-r… Show more
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