The effect of surface chemistry on anti-soiling properties of transparent perfluoroalkyl and alkyl modified silica coatings

Taheri, Saba; Motlagh, Fatemeh Hosseinpour; Dehestanizad, Sina; Yahyaei, Hossein; Motallebzadeh, Amir; Zarrabi, Ali; Tehrani, Abolfazl Golmohammadian; Khodabakhsh, Mohammadreza; Makki, Hesam

doi:10.1016/j.surfin.2022.101824

Cited by 6 publications

(8 citation statements)

References 65 publications

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“…The coated surface can weaken the interfacial adhesion between dust and surface and allow dust particles to be easily removed at low fluid shear [ 26 ], thus obtaining anti-dust properties. Among the known materials, fluorinated materials are considered to have the lowest surface energy; therefore, the addition of fluorinated materials can effectively reduce the surface energy [ 98 , 107 ].…”

Section: Methods For Creating Anti-dust and Easy-cleaning Surfacesmentioning

confidence: 99%

“…To explore the effect of surface energy alone on anti-dust properties, Taheri et al [ 107 ] synthesized a set of hydrophobic coatings with controlled surface chemistry using fluoroalkylsilanes. As shown in Figure 8 a, the surface of the coatings is extremely flat with almost no micro-/nanostructure, and the roughness can be kept below 1 nm.…”

Section: Methods For Creating Anti-dust and Easy-cleaning Surfacesmentioning

confidence: 99%

“…( b ) Surface energy of the coating and ( c ) optical micrographs after dust-fall experiments, reproduced with permission from Ref. [ 107 ].…”

Section: Figurementioning

confidence: 99%

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Progress in Studies of Surface Nanotextures and Coatings with Nanomaterials on Glass for Anti-Dust Functionality

Wang

Liu

2022

Nanomaterials

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Dust pollution presents a wide range of adverse effects to product functionalities and the quality of human life. For instance, when dust particles deposit on solar photovoltaic panels, sunlight absorption is significantly reduced, and solar-to-electrical energy conversion yield may be lowered by 51%- Conventional (manual) dust removal methods are costly, consume significant material resources, and cause irreparable damage to the solar glass surface. Therefore, it is critical to develop glass surfaces that can clean themselves or are easily cleaned by natural forces. Many approaches have been attempted to reduce dust deposition, such as developing superhydrophobic surfaces and preparing anti-static surfaces. This paper reviews the recent progress in studies of anti-dust and cleaning mechanisms or methodologies, which include investigation into micro- and nano-sized dust properties, dust deposition processes and adhesion mechanisms to surfaces, and the state-of-the-art approaches to anti-dust and easy-cleaning functions that tailor surface micro-/nanotextures, lowering surface energy via nanocoatings, and enhancing anti-static properties with nanomaterials. We compare the advantages and disadvantages of various approaches and discuss the research prospects. We envision that future research will be focused on developing transparent surfaces with multiple dust-proof functions to cope with dust-burdening operating environments.

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Section: Methods For Creating Anti-dust and Easy-cleaning Surfacesmentioning

confidence: 99%

Section: Methods For Creating Anti-dust and Easy-cleaning Surfacesmentioning

confidence: 99%

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Progress in Studies of Surface Nanotextures and Coatings with Nanomaterials on Glass for Anti-Dust Functionality

Wang

Liu

2022

Nanomaterials

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“…Chemical composition and surface morphology are two important factors determining the surface properties of polymer coatings such as wettability, a critical surface property for a wide range of applications, including anti-icing, 1,2 anticorrosion, 2,3 antisoiling, 4,5 antibacterial, 6,7 and antibiofouling coatings. 8−11 Surface morphology and composition might differ from the bulk due to the surface rearrangements of polymer chains.…”

Section: ■ Introductionmentioning

confidence: 99%

Molecular Insight into the Effect of Polymer Topology on Wettability of Block Copolymers: The Case of Amphiphilic Polyurethanes

Mirzaalipour,

Aghamohammadi,

Vakili

et al. 2023

Langmuir

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The microstructure design of multiblock copolymers is essential for achieving desired interfacial properties in submerged applications. Two major design factors are the chemical composition and polymer topology. Despite a clear relationship between chemical composition and wetting, the effect of polymer topology (i.e., linear vs cross-linked polymers) is not very clear. Thus, in this study, we shed light on the molecular origins of polymer topology on the wetting behavior. To this end, we synthesized linear and three-dimensional (3D) cross-linked network topologies of poly(ethylene glycol) (PEG)-modified polycarbonate polyurethanes with the same amount of hydrophilic PEG groups on the surface (confirmed by X-ray photoelectron spectroscopy (XPS)) and studied the wetting mechanisms through water contact angle (WCA), atomic force microscopy (AFM), and molecular dynamics (MD) simulations. The linear topology exhibited superhydrophilic behavior, while the WCA of the cross-linked polymer was around 50°. AFM analysis (performed on dry and wet samples) suggests that PEG migration toward the interface is the dominant factor. MD simulations confirm the AFM results and unravel the mechanisms: the higher flexibility of PEG in linear topology results in a greater PEG migration to the interface and formation of a thicker interfacial layer (i.e., twice as thick as the cross-linked polymers). Accordingly, water diffusion into the interfacial layer was greater in the case of the linear polymer, leading to better screening of the underneath hydrophobic (polycarbonate) segments.

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“…4,5 At the same time, it can also enhance the bonding ability between metal matrix and organic coating. 6,7 SiO 2 nanoparticles are a hydrophilic and attractive material for superhydrophobic coatings which have –OH group on the surface due to cheaper, 8 chemically stable, 9 harmless, and low thermal conductivity. 10 Thus, we can modify SiO 2 molecules to obtain a stable superhydrophobic coating and study its reaction mechanism.…”

Section: Introductionmentioning

confidence: 99%

Preparation of SiO₂ resin coating with superhydrophobic wettability and anti-icing behavior analysis

et al. 2022

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The effect of surface chemistry on anti-soiling properties of transparent perfluoroalkyl and alkyl modified silica coatings

Cited by 6 publications

References 65 publications

Progress in Studies of Surface Nanotextures and Coatings with Nanomaterials on Glass for Anti-Dust Functionality

Progress in Studies of Surface Nanotextures and Coatings with Nanomaterials on Glass for Anti-Dust Functionality

Molecular Insight into the Effect of Polymer Topology on Wettability of Block Copolymers: The Case of Amphiphilic Polyurethanes

Preparation of SiO₂ resin coating with superhydrophobic wettability and anti-icing behavior analysis

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The effect of surface chemistry on anti-soiling properties of transparent perfluoroalkyl and alkyl modified silica coatings

Cited by 6 publications

References 65 publications

Progress in Studies of Surface Nanotextures and Coatings with Nanomaterials on Glass for Anti-Dust Functionality

Progress in Studies of Surface Nanotextures and Coatings with Nanomaterials on Glass for Anti-Dust Functionality

Molecular Insight into the Effect of Polymer Topology on Wettability of Block Copolymers: The Case of Amphiphilic Polyurethanes

Preparation of SiO2 resin coating with superhydrophobic wettability and anti-icing behavior analysis

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Product

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Preparation of SiO₂ resin coating with superhydrophobic wettability and anti-icing behavior analysis