In this work, the effect of ultrasonic
pretreatment time on oxidized coal flotation was studied. Analytical
techniques, such as particle size distribution (PSD), scanning electron
microscopy (SEM), X-ray photoelectron spectroscopy (XPS), contact
angle measurement, and specific surface area/pore analysis, were used
to examine the changes in the physicochemical characteristics of the
coal samples before and after ultrasonic pretreatment. The results
showed that the flotation kinetics and yield of the clean coal initially
increased with ultrasonic pretreatment time. The maximum clean coal
yield (79.6%) and maximum value of the flotation kinetics constant
were obtained within 10 min of ultrasonic pretreatment. The hydrophilic
oxidized layer on the coal surface was effectively removed by ultrasonic
cavitation, as identified by PSD, SEM, XPS, and contact angle, which
increased the flotability and recovery of oxidized coal. However,
prolonged ultrasonic pretreatment proved detrimental to oxidized coal
flotation. The fresh exposed surface was reoxidized by the hydroxyl
free radicals produced during the cavitation process. It is expected
that the results of this work will provide guidance in ultrasonic
flotation for oxidized coal.