2007
DOI: 10.1016/j.matchemphys.2007.05.046
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The effect of some lactones as inhibitors for the corrosion of mild steel in 1M hydrochloric acid

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Cited by 106 publications
(39 citation statements)
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“…It can be seen in the table that Ea is higher in the presence of the inhibitors than in their absence. The modification in the values of Ea may be attributed to the geometric blocking effect of adsorbed inhibitive species on the metal surface [33]. This observation further supports the proposed physisorption mechanism as reported by [34] The values of ∆H and ∆S are given in Table 7.…”
Section: Effect Of Temperature and Activation Parameters Of Inhibitiosupporting
confidence: 85%
“…It can be seen in the table that Ea is higher in the presence of the inhibitors than in their absence. The modification in the values of Ea may be attributed to the geometric blocking effect of adsorbed inhibitive species on the metal surface [33]. This observation further supports the proposed physisorption mechanism as reported by [34] The values of ∆H and ∆S are given in Table 7.…”
Section: Effect Of Temperature and Activation Parameters Of Inhibitiosupporting
confidence: 85%
“…The values of activation energy enumerated in Table 6 are higher in the presence of the SSE than in its absence. It may be attributed to the geometric blocking effect of adsorbed inhibitive species on the metal surface [28]. Further inspection of Table 6 also revealed that Ea increases with increase in SSE concentration.…”
Section: Activation Parameters Of the Corrosion Processmentioning
confidence: 88%
“…This means that the corrosion reaction will further be pushed to surface sites that are characterized by progressively higher values of Ea in the presence of extracts [29]. The enthalpy, DH ads 0 and entropy, DS ads 0 of activation for the corrosion process, the alternative formulation of Arrhenius equation was used [28,29]:…”
Section: Activation Parameters Of the Corrosion Processmentioning
confidence: 99%
“…Activation energy was calculated from the Arrhenius relation, i.e., plot of ln υ corr vs 1000/T (Figure 1). 26 Both activation entropy and enthalpy (∆S* and ∆H*) were determined from transition state diagram (Figure 2), 27 i.e., plot of ln υ corr vs 1000/T. Table 4 shows that the values for corrosion inhibition process are higher compared to 0.…”
Section: Weight Loss (Gravimetric) Studiesmentioning
confidence: 99%