Need for better understanding and more accurate estimation of radiative fluxes in urban environments, specifically urban surface albedo and exitance, motivates development of new remote sensing and three-dimensional (3D) radiative transfer (RT) modeling methods. The discrete anisotropic radiative transfer (DART) model, one of the most comprehensive physically based 3D models simulating Earth/atmosphere radiation interactions, was used in combination with satellite data (e.g., Landsat-8 observations) to better parameterize the radiative budget components of cities, such as Basel in Switzerland. After presenting DART and its recent RT modeling functions, we present a methodological concept for estimating urban fluxes using any satellite image data.