To reveal the distribution of atmospheric tritium water
(HTO) vapor
and provide a baseline for tritium pollution control, a subnational
survey was conducted in mainland China. As the largest study on HTO
vapor in China that has ever been formally reported, this study provides
a macroimpression of the atmospheric HTO specific activity from March
2017 to March 2018. A total of 102 passive samplers were deployed
at 34 sites in 30 provinces to determine the seasonal and spatial
distributions of HTO vapor. In general, the HTO specific activity
in the atmosphere ranged from lower than the minimum detectable activity
(0.18 Bq·L–1) to 5.5 Bq·L–1. Spatially, the specific activity of HTO was positively correlated
to the latitude and the distance to proximal coastline. Seasonally,
significantly higher HTO specific activities were observed in spring
and relatively lower in summer. Based on correlation analysis, the
atmospheric HTO distributions were considered to be the consequence
of combined factors of the stratospheric–tropospheric net mass
flux, the distance from the tropopause to the ground, the fraction
of air mass that originated from ocean re-evaporation and long-distance
transport from high-latitude continents.