The Effect of Processing Parameters and Calcium-stearate on the Ejection Process of Injection Molded Poly(Lactic Acid) Products

Abstract

We investigated the ejection/demolding of continuous production of injection molded Poly(Lactic Acid) tensile testing specimens and analyzed the effect of 1 wt% Calcium-Stearate additive as demolding agent (sliding or mold release agent) on this process. We demonstrated that the Poly(Lactic Acid) specimens could get stuck in the mold or even break during demolding during continuous injection molding in a certain type of mold, which has a low draft angle and varying cavity width along the flow path. The standard dumbbell-shaped tensile testing specimen is produced in such a mold. Demolding was rated with the use of a high-speed camera into three categories (problem-free demolding / stuck, but demolded undamaged product / stuck and damaged product). Moreover, the ejector force required to push the product out of the cavity was monitored over 30 continuous injection molding cycles. We also investigated the effect of processing parameters, such as injection rate (screw speed), holding pressure, holding time, mold temperature, melt temperature, backpressure, screw rotational speed, and pre-process drying (drying or not drying the pellets before injection molding). We managed to avoid product breakage during demolding with the proper settings of certain process parameters and the use of Calcium-Stearate, an effective demolding agent. This ensured problem-free demolding and thus continuous injection molding.

Effect of Processing Parameters and Wall Thickness on the Strength of Injection Molded Products

“…The best way to control the process is to use sensors in the mold [4,5]. In case of injection molding, melt temperature, mold temperature, injection rate, holding time, and holding pressure significantly affect the properties of injection molded parts [6][7][8][9][10][11][12][13].…”

Effects of carbon‐based nanoparticles on the properties of poly(lactic acid) hybrid composites containing basalt fibers and carbon‐based nanoparticles processed by injection molding

“…However, plasticizers can improve its flexibility. [5][6][7][8][9][10][11][12][13][14] Unfortunately, PLA often does not have suitable properties to be used as a structural material, but with reinforcement and additives, its mechanical properties can be greatly improved and it can be made suitable for engineering applications. 15 One promising reinforcing material is basalt fiber.…”

“…PLA is a rigid material with an elongation at break of only 2%–5%. However, plasticizers can improve its flexibility 5–14 …”

On the Production of Poly(Lactic Acid) (PLA) Compounds with Metallic Stearates Based on Zinc, Magnesium and Cobalt. Investigation of Torque Rheometry and Thermal Properties

“…Tábi and Poloskei 51 evaluated the effect of incorporating 1% by weight of calcium stearate in the PLA matrix, aiming to understand the impact during injection molding. The authors found that the molding process improved and prevented defects in the samples, suggesting that calcium stearate was effective as a demolding agent.…”