“…The organic cations in the clay mineral galleries may markedly affect the stability of the mineral to mechanical treatment. Organoclays may be less or more resistant toward mechanical treatment than natural clays independent of the character of the organic cations [32].…”
“…The organic cations in the clay mineral galleries may markedly affect the stability of the mineral to mechanical treatment. Organoclays may be less or more resistant toward mechanical treatment than natural clays independent of the character of the organic cations [32].…”
“…The DTG curves of PS shows a well-defined strong symmetric double peak near 96 and 163°C, characteristic for montmorillonites [27,35]. It reflects the release if water adsorbed on the particle surfaces and of water molecules coordinating Ca 2+ or Na + cations, respectively.…”
Section: Thermogravimetry Analysismentioning
confidence: 93%
“…8a-d. For PS samples, it shows the main adsorption bands as follows: 468, 522, 584, 645, 713, 778, 875, 1035, 1421, 1635, 3421 and 3620 cm À1 . The bands due to free (or weakly hydrogen-bonded water molecules to the surface oxygen of tetrahedral sheet) water molecules, water-water hydrogen bond (M n+ -O-H-O-H-) and water bending modes are observed near 3622, 3421 and 1635 cm À1 , respectively [27,28]. The peaks at 1421, 875 and 713 cm À1 are attributed to anti-symmetric stretching and out-ofplane bending modes of CO 3 2À ions [29].…”
“…Two peaks at 3620 and 3428 cm −1 are attributed to the stretching of -OH, which is the result of the presence of water in nanoclay montmorillonite. The peak at 1030 cm −1 is resulted from the stretching vibrations of Si-O and the peaks at 520 and 470 cm −1 are resulted from the bending absorptions of Si-O and Al-O bonds in the MMT structure (Hrachova et al, 2007;Su et al, 2008). In the spectra of MMT/BB (5) and MMT/BB (25), new peaks appeared at 2925 and 2851 cm −1…”
This study evaluates the effectiveness of using a Bio-modified Nanoclay additive (BNC) to reduce the oxidative aging of asphalt pavements. The study results through X-Ray Diffraction analysis showed that the modification of montmorillonite clay with bio-modifier increased the basal d-spacing of clay. The resulting nanoclay with increased interlayer spacing was chosen for application in asphalt binder. Rheological characterization of clay-modified asphalt binder were studied before and after oxidation aging. The effects of BNC on asphalt complex modulus were observed to be prevailing in the intermediate to high-temperature range. The aging resistance of asphalt binder showed improvement with the addition of nanoclay and the improvement was more notable in presence of bio modified-nanoclay than pure clay.
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