The Effect of Immersion Time and Immersion Temperature on the Corrosion Behavior of Zinc Phosphate Conversion Coatings on Carbon Steel

Asadi, Vahid; Danaee, I.; Ebrahimi, Hadi

doi:10.1590/1516-1439.343814

Cited by 28 publications

(14 citation statements)

References 30 publications

(37 reference statements)

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“…In general, the phosphate coating improves the corrosion resistance of a substrate. However, noticeable improvement in corrosion resistance is not observed during the stage of induction and commencement of film growth, which are the stages from the start of the phosphate treatment to 3 min [21,22]. Since the phosphating time in this study was within 2 min, the EIS results indicate that phosphate crystals had not sufficiently formed to be able to improve corrosion resistance for both types of inorganic acid.…”

Section: Electrochemical Imedance Spectroscopymentioning

confidence: 84%

Optimization of Pickling Solution for Improving the Phosphatability of Advanced High-Strength Steels

Cho

Yoo

et al. 2021

Materials

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This study investigated the optimum pickling conditions for improving the phosphatability of advanced high-strength steel (AHSS) using surface analysis and electrochemical measurements. To remove the SiO2 that forms on the surface of AHSS, 30 wt.% NH4HF2 was added to the pickling solution, resulting in a significant reduction in the amount of SiO2 remaining on the surface of the AHSS. The phosphatability was improved remarkably using HNO3 concentrations higher than 13% in the pickling solution. Furthermore, phosphate crystals became finer after pickling with a HNO3-based solution rather than a HCl-based solution. Electrochemical impedance spectroscopy (EIS) data indicated that the corrosion resistance of AHSS subjected to HNO3-based pickling was higher than that of AHSS subjected to HCl-based pickling. Fluorine compounds, which were involved in the phosphate treatment process, were only formed on the surface of steel in HNO3-based solutions. The F compounds reacted with the phosphate solution to increase the pH of the bulk solution, which greatly improved the phosphatability. The phosphatability was better under HNO3-based conditions than a HCl-based condition due to the fineness of the phosphate structure and the increased surface roughness.

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Section: Electrochemical Imedance Spectroscopymentioning

confidence: 84%

Optimization of Pickling Solution for Improving the Phosphatability of Advanced High-Strength Steels

Cho

Yoo

et al. 2021

Materials

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“…Based on figures 6(B)-(D), the surface of phosphate coating has finer and tiny crystals with continuous and compact structure. The presence of internal stress in Zn-P coated mild steel led to the formation of pores [27]. Due to this event the surface of the Zn-P coated, Zn-P coated TAE and Zn-P coated TME mild steel was further analyzed with 20,000 x magnification as shown in figures 7-9, respectively.…”

Section: Potentiodynamic Polarizationmentioning

confidence: 99%

Mangrove bark tannins as a Zn–P coating sealant for mild steel corrosion protection in 3.5% NaCl solution

Abidin

Hussin

2020

Mater. Res. Express

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In this work, mangrove bark tannins have been studied as a sealant after Zn-P of mild steel. The efficiency of the sealant against the corrosion was tested by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarisation (PD) in 3.5% NaCl solution. The increased in the concentration of the tannin as a sealant increases the inhibition efficiency up to optimum concentration of 4 g l −1 . The inhibition efficiencies of tannin methanol extract (TME) and 70% tannin acetone extract (TAE) were 83.52% and 71.12% respectively. The results obtained from EIS and PD were in a good agreement and complementary to each other. The double layer constant phase element capacitance (CPE dl ) decrease indicated that a film form on the surface of the mild steel that retard the corrosion activities. Further, the pore modifications and elemental compositions were analyzed by scanning electron microscope (SEM) and energy dispersive x-ray (EDX).

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“…Guenbour A. et al [ 23 ] studied the corrosion resistance properties of steel on the surface, of which a layer of epoxy or chlorinated rubber was deposited, into which zinc phosphate was added. Asadi V. et al [ 24 ] studied the immersion behavior for different periods of coated samples: phosphate with a zinc oxide solution. Moller H. et al [ 25 ] studied the corrosion behavior of carbon steel immersed in natural and synthetic waters, highlighting chemical compounds that appeared on the surface using X-ray diffraction (XRD).…”

Section: Introductionmentioning

confidence: 99%

Immersion Behavior of Carbon Steel, Phosphate Carbon Steel and Phosphate and Painted Carbon Steel in Saltwater

2021

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The carbon steel is used in many areas due to its good mechanical properties; however, its low corrosion resistance presents a very important problem, for example, when carbon steel carabiners are used in the petroleum industry or navy, the possibility of an accident is higher due to carabiner failure. This phenomenon could occur as a consequence of the corrosion process which negatively affects mechanical properties. This paper study the possibility to improve its corrosion resistance by depositing on its surface a phosphate layer and a paint layer, and also aims to analyze the immersion behavior in saltwater of carbon steel, phosphate carbon steel, and phosphate and painted carbon steel. According to this study, by coating the carbon steel with a phosphate or paint layer, a higher polarization resistance is obtained in saltwater. Moreover, by electrochemical impedance spectroscopy (EIS), it was observed that the corrosion rate decreases with the increase of the immersion time. Meanwhile scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) revealed that the main compounds which formed on the sample’s surface were iron oxides or hydroxy-oxides, after immersion for a longer period. The overall results show that all types of deposited layers increase the corrosion resistance of C45 steel.

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The Effect of Immersion Time and Immersion Temperature on the Corrosion Behavior of Zinc Phosphate Conversion Coatings on Carbon Steel

Cited by 28 publications

References 30 publications

Optimization of Pickling Solution for Improving the Phosphatability of Advanced High-Strength Steels

Optimization of Pickling Solution for Improving the Phosphatability of Advanced High-Strength Steels

Mangrove bark tannins as a Zn–P coating sealant for mild steel corrosion protection in 3.5% NaCl solution

Immersion Behavior of Carbon Steel, Phosphate Carbon Steel and Phosphate and Painted Carbon Steel in Saltwater

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