The Effect of Hydrothermal, Microwave, and Mechanochemical Treatments of Tin Phosphate on Sorption of Some Cations

Abstract

The samples of precipitated tin (IV) phosphate, modified using hydrothermal, microwave, and mechanochemical procedures, were studied in the process of Cs(I), Sr(II), and U(VI) ion sorption. The initial and modified samples were investigated before and after sorption using XRD, XRF, FTIR, and nitrogen adsorption–desorption. It was found that the modification procedures transformed the micro-mesoporous structure of the initial sample into a meso–macroporous structure. As a result, the sorption capacity in relation to all ions increases several times. This indicates the determining role of the porous structure, primary content, and mesopore size on the sorption activity of tin phosphate. The samples, treated in the form of a wet gel, which is a novel procedure, showed the maximum sorption indicators. The sorption of all the tested ions is described by the Langmuir isotherm.

The Effect of High-Energy Ball Milling of Montmorillonite for Adsorptive Removal of Cesium, Strontium, and Uranium Ions from Aqueous Solution

“…When grinding solids using energy-intensive equipment, it is possible to achieve a high dispersion of final products, as well as to significantly influence the concentration and nature of surface defects. The latter determines the use of mechanochemical activation (MCA) in the technology of catalysts as well as in sorption processes [23][24][25][26].…”