The effect of geometric factor of carbon nanofillers on the electrical conductivity and electromagnetic interference shielding properties of poly(trimethylene terephthalate) composites: a comparative study

Huang, Chien‐Lin; Wang, Yu-Jyun; Fan, Yang‐Chun; Hung, Ching Hsia; Liu, Yu‐Chia

doi:10.1007/s10853-016-0549-5

Cited by 28 publications

(18 citation statements)

References 71 publications

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“…According to the manufacturer, the average thickness of the GNS was 3 nm. The PTT and GNSs had densities of 1.28 and 2.20 g/cm 3 [21], respectively. The GNSs were added to the o -DCB-phenol (1:1, v / v ) solvent, after which ultrasonic treatment was performed for 6 h. Weighed PTT pellets were then added.…”

Section: Methodsmentioning

confidence: 99%

“…The percolation equation is typically expressed as P ~ (ϕ − ϕ c ) β [19,20], where P is the asymptotic behavior of a material property, ϕ is the filler volume fraction, β is the critical scaling exponent, and ϕ c is the fraction threshold. A filler network is formed that is higher than ϕ c , based on our previous study [21] where the percolated filler–filler network in composites in which the percolation exponent and threshold change was correlated with the filler geometric structure. Mazinani et al [22] reported a polystyrene (PS) composite fiber filled with different contents and types of CNT.…”

Section: Introductionmentioning

confidence: 99%

“…The cold crystallization of the PTT composites was retarded by the GNSs. Moreover, the percolation exponent and threshold of the PTT/GNS composites are larger than those of the PTT/CNT composites [21]. In the electrospun PTT/CNT composite fibers, the aspect ratio and functionalized group of CNT affects the morphology of the resulting fibers [30].…”

Section: Introductionmentioning

confidence: 99%

“…Wu et al [30] reported that PTT/CNT composites could be prepared via melt compounding for electrospinning. Moreover, PTT composites filled with GNS could be prepared through coagulation by using ortho -dichlorobenzene ( o -DCB)-phenol as a solvent to obtain low electrical percolation thresholds of 0.53 and 0.84 vol % in GNS with different aspect ratios [21,29]. Coagulation should work better than melt compounding for GNS to be well dispersed and incorporated in thermoplastic polymer matrices because the low solution viscosity improves the polymer chain diffusion into the GNS interstices.…”

Section: Introductionmentioning

confidence: 99%

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Electrospun Graphene Nanosheet-Filled Poly(Trimethylene Terephthalate) Composite Fibers: Effects of the Graphene Nanosheet Content on Morphologies, Electrical Conductivity, Crystallization Behavior, and Mechanical Properties

Huang¹,

Wu²,

Jeng³

et al. 2019

Polymers

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In this study the effects of increased graphene nanosheet (GNS) concentration on variations in the structure and properties of electrospun GNS-filled poly(trimethylene terephthalate) (PTT/GNS) composite fiber, such as its morphologies, crystallization behavior, mechanical properties, and electrical conductivity, were investigated. The effects of GNS addition on solution rheology and conductivity were also investigated. GNSs were embedded in the fibers and formed protrusions. The PTT cold crystallization rate of PTT/GNS composite fibers increased with the gradual addition of GNSs. A PTT mesomorphic phase was formed during electrospinning, and GNSs could induce the PTT mesomorphic phase significantly during PTT/GNS composite fiber electrospinning. The PTT/GNS composite fiber mats (CFMs) became ductile with the addition of GNSs. The elastic recoveries of the PTT/GNS CFMs with 170 °C annealing were better than those of the as-spun PTT/GNS CFMs. Percolation scaling laws were applied to the magnitude of conductivity to reveal the percolation network of electrospun PTT/GNS CFMs. The electrical conductivity mechanism of the PTT/GNS CFMs differed from that of the PTT/GNS composite films. Results showed that the porous structure of the PTT CFMs influenced the performance of the mats in terms of electrical conductivity.

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Section: Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Electrospun Graphene Nanosheet-Filled Poly(Trimethylene Terephthalate) Composite Fibers: Effects of the Graphene Nanosheet Content on Morphologies, Electrical Conductivity, Crystallization Behavior, and Mechanical Properties

Huang¹,

Wu²,

Jeng³

et al. 2019

Polymers

Self Cite

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“…Huang et al [6] modeled the effect of the geometric factor on the conductivity of composites containing CNTs and GNPs. In general, due to the higher aspect ratio, CNTs are believed more effective than GNPs for achieving the percolation threshold [7,8], but the method adopted for the fabrication of the composite in this case also entails great importance.…”

Section: Introductionmentioning

confidence: 99%

Laser Treatments for Improving Electrical Conductivity and Piezoresistive Behavior of Polymer–Carbon Nanofiller Composites

et al. 2019

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The effect of carbon nanotubes, graphene-like platelets, and another carbonaceous fillers of natural origin on the electrical conductivity of polymeric materials was studied. With the aim of keeping the filler content and the material cost as low as possible, the effect of laser surface treatments on the conductivity of polymer composites with filler load below the percolation threshold was also investigated. These treatments allowed processing in situ conductive tracks on the surface of insulating polymer-based materials. The importance of the kinds of fillers and matrices, and of the laser process parameters was studied. Carbon nanotubes were also used to obtain piezoresistive composites. The electrical response of these materials to a mechanical load was investigated in view of their exploitation for the production of pressure sensors and switches based on the piezoresistive effect. It was found that the piezoresistive behavior of composites with very low filler concentration can be improved with proper laser treatments.

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Electrically Insulating Flexible Films with Quasi‐1D van der Waals Fillers as Efficient Electromagnetic Shields in the GHz and Sub‐THz Frequency Bands

et al. 2021

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Polymer composite films containing fillers comprising quasi‐1D van der Waals materials, specifically transition metal trichalcogenides with 1D structural motifs that enable their exfoliation into bundles of atomic threads, are reported. These nanostructures are characterized by extremely large aspect ratios of up to ≈106. The polymer composites with low loadings of quasi‐1D TaSe3 fillers (<3 vol%) reveal excellent electromagnetic interference shielding in the X‐band GHz and extremely high frequency sub‐THz frequency ranges, while remaining DC electrically insulating. The unique electromagnetic shielding characteristics of these films are attributed to effective coupling of the electromagnetic waves to the high‐aspect‐ratio electrically conductive TaSe3 atomic‐thread bundles even when the filler concentration is below the electrical percolation threshold. These novel films are promising for high‐frequency communication technologies, which require electromagnetic shielding films that are flexible, lightweight, corrosion resistant, inexpensive, and electrically insulating.

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The effect of geometric factor of carbon nanofillers on the electrical conductivity and electromagnetic interference shielding properties of poly(trimethylene terephthalate) composites: a comparative study

Cited by 28 publications

References 71 publications

Electrospun Graphene Nanosheet-Filled Poly(Trimethylene Terephthalate) Composite Fibers: Effects of the Graphene Nanosheet Content on Morphologies, Electrical Conductivity, Crystallization Behavior, and Mechanical Properties

Electrospun Graphene Nanosheet-Filled Poly(Trimethylene Terephthalate) Composite Fibers: Effects of the Graphene Nanosheet Content on Morphologies, Electrical Conductivity, Crystallization Behavior, and Mechanical Properties

Laser Treatments for Improving Electrical Conductivity and Piezoresistive Behavior of Polymer–Carbon Nanofiller Composites

Electrically Insulating Flexible Films with Quasi‐1D van der Waals Fillers as Efficient Electromagnetic Shields in the GHz and Sub‐THz Frequency Bands

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