The Effect of Electron-withdrawing Group Functionalization on Antibacterial and Catalytic Activity of Palladium(II) Complexes

Feng, Zhiqiang; Yang, Xiaoli; Ye, Yuanfeng; Hao, Lin-Yun

doi:10.5012/bkcs.2014.35.4.1121

Cited by 13 publications

(2 citation statements)

References 22 publications

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“…Over the last decade, the exploration of electronic effect on the properties of metal complexes has been dramatically increased owning to its easy-monitored nature by various methods ( Allen and Cook, 1963 ; Lanznaster et al, 2006 ; Kieltsch et al, 2010 ; Feng et al, 2014 ; Chen et al, 2015 ; Bellows et al, 2016 ; Matheu et al, 2019a ; Meza-Chincha et al, 2020 ). It is worth to note that the electronic effect can usually be reflected by the Hammette parameter σ (σ m or σ p , depending on the position of substituent), which increases with the increasing of electron-withdrawing ability.…”

Section: Substituent-modification Strategies Of Ligandsmentioning

confidence: 99%

Ligands modification strategies for mononuclear water splitting catalysts

Wang

2022

Front. Chem.

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Artificial photosynthesis (AP) has been proved to be a promising way of alleviating global climate change and energy crisis. Among various materials for AP, molecular complexes play an important role due to their favorable efficiency, stability, and activity. As a result of its importance, the topic has been extensively reviewed, however, most of them paid attention to the designs and preparations of complexes and their water splitting mechanisms. In fact, ligands design and preparation also play an important role in metal complexes’ properties and catalysis performance. In this review, we focus on the ligands that are suitable for designing mononuclear catalysts for water splitting, providing a coherent discussion at the strategic level because of the availability of various activity studies for the selected complexes. Two main designing strategies for ligands in molecular catalysts, substituents modification and backbone construction, are discussed in detail in terms of their potentials for water splitting catalysts.

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Section: Substituent-modification Strategies Of Ligandsmentioning

confidence: 99%

Ligands modification strategies for mononuclear water splitting catalysts

Wang

2022

Front. Chem.

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“…21 In addition, the strong electron-withdrawing effect caused by C-Cl bonds can inhibit bacteria to a certain extent. [25][26][27] Hence, these advantageous properties of PCP against E. coli are mainly due to the appropriate roughness and surface chemical composition. Because parylene C and D have similar C-Cl bonds, the poor anti-adhesion activity of PDP against E. coli was unexpected (Fig.…”

Section: Bacterial Adhesion Propertiesmentioning

confidence: 99%

Bacterial adhesion properties of parylene C and D deposited on polydimethylsiloxane

et al. 2022

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Palladium complexes containing imino phenoxide ligands: synthesis, luminescence, and their use as catalysts for the ring-opening polymerization of rac-lactide

et al. 2017

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The preparation, structural characterization, luminescence, and catalytic activity of three palladium(II) complexes bearing imino phenoxide ligands are reported. The X-ray studies revealed that the complexes are mononuclear with palladium centres coordinated in a square-planar coordination environment. Two of the complexes are emissive in solution at room temperature. The catalytic activities towards the ring-opening polymerization of rac-lactide (rac-LA) were tested. Polymers with moderate molecular weights and relatively broad dispersity (Ð) were obtained. Kinetic studies revealed that the polymerization followed first-order kinetics.Graphical abstract Electronic supplementary materialThe online version of this article (10.1007/s00706-017-2119-1) contains supplementary material, which is available to authorized users.

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The Effect of Electron-withdrawing Group Functionalization on Antibacterial and Catalytic Activity of Palladium(II) Complexes

Cited by 13 publications

References 22 publications

Ligands modification strategies for mononuclear water splitting catalysts

Ligands modification strategies for mononuclear water splitting catalysts

Bacterial adhesion properties of parylene C and D deposited on polydimethylsiloxane

Palladium complexes containing imino phenoxide ligands: synthesis, luminescence, and their use as catalysts for the ring-opening polymerization of rac-lactide

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